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36 Cards in this Set

  • Front
  • Back

Protons

*Postive (+e)


*In nucleus of atom


*# of protons=atomic number (Z)

Neutrons

*Neutral


*In nucleus of atom


*Mass only slightly larger than a proton's

Electron

*Negative (-e)


*Move through the space surrounding nucleus


*Associated with varying levels of energy


*Much smaller mass than proton's and neutron's

Valence electrons

*Electrons furthest from the nucleus


*Have strongest interactions with surrounding environment and weakest with nucleus


*Involved in bonds with other atoms


*Determine the reactivity of the atom

Atomic number (Z)

equals the number of protons found in an atom (number above the atom letter in the periodic table and the number in the lower left corner for written atom letters)

Mass number (A)

sum of the protons and neutrons in an atom (number in upper left corner of written atom)

Isotope

*Atoms that share an atomic number but have different mass numbers


*Same number of protons (so same atom), but different number of neutrons


*Name isotopes with element name followed by mass number (ex. carbon-12, iodine-131)

Atomic mass

nearly equal to the mass number, the sum of protons and neutrons

protium

*Isotope of hydrogen


*One proton

deuterium

*Isotope of hydrogen


*One proton and one neutron

tritium

*Isotope of hydrogen


*One proton and two neutrons

Atomic weight

*Weighted average of an atom's different isotopes


*Reported on periodic table under element


*No atoms have this exact mass (it's an average)

Avogadro's number

NA=6.022x10^23 particles

Planck's relation (for quantized energy)

E=hf

Planck's constant

h=6.626x10^-34 Js

Equation for the energy of the electron orbiting a hydrogen nucleus

E= -RH/n^2

Rydberg unit of energy (RH)

2.18x10^-18 J/electron

Does the energy of an electron increase or decrease the further out from the nucleus that it's located?

Increases

Does the energy of an electron become more or less negative the further out from the nucleus that it's located?

Becomes less negative (Energy increases)

What color do we see for compounds?

We see the color of the light that is NOT absorbed by the compound

Heisenberg's uncertainty principle

It's impossible to determine, with perfect accuracy, the momentum and the position of an electron

Pauli exclusion principle

No two electrons in a given atom can possess the same set of four quantum numbers

Maximum number of electrons within a shell

2n^2

Maximum number of electrons within a subshell

4l+2

principal quantum number (n)

Shells

Angular momentum quantum number (l)

the shape of subshells (n-1)


(0=s, 1=p, 2=d, 3=f)

Magnetic quantum number (ml)

the orbital within a subshell where the electron is most likely to be found (between -l and +l, including 0)

Electron configuration for Chromium (Z=24) and other elements in its group

[Ar]4s^1 3d^5......


(would have normally been [Ar]4s^2 3d^4 but want 3d subshell to be half-filled for extra stability)

Electron configuration for Copper (Z=29) and other elements in its group

[Ar]4s^1 3d^10......


(would have normally been [Ar]4s^2 3d^9 but want a full d subshell for extra stability)

paramagnetic

*Materials composed of atoms with unpaired electrons


*A magnetic field will cause parallel spins in unpaired electrons and therefore cause an attraction

diamagnetic

materials composed of atoms with only paired electrons (will be slightly repelled by a magnetic field)

Balmer series

transitions from upper levels (n>2) to n=2

Lyman series

transitions from upper levels (n>1) to n=1

Hund's rule

Within a given subshell, orbitals are filled such that there are a maximum number of half-filled orbitals with parallel spins