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21 Cards in this Set

  • Front
  • Back

What is the SI unit for pressure

it is pascals, 1 atm= 101.325 pascals.

what is the STP (standard temperature and pressure for a gas)

it is at 273 K (0 celisus) and 1ATM.

Standard state conditions is for enthlapy and entropy an free energy changes and are?

298 K. and 1M concentration AND 1 atm.

IDEAL gas

PV=nRT.

Combined gas law/ what is it and where is it used

used to find the change in the volume or pressure or temp from the standard.

avogadro's principle

at constant temperature and pressure, as number of moles increases the volume increases as well.




N/V= n2/V2.




K(which in this case is constant pressure over constant temperature) = N/V.




derive it from Ideal gas law its not hard.

Boyle's law

P goes up, V goes down and vice versa in constant temperature.

Charles' law

V/T =V/T




K= V/T

Gay-Lussac's law

If constant volume and moles, then Pressure increases with temperature.

Combined Gas law.

PV/T.

Dalton's law of partial pressure.

In a container that contains a mixture of gasses, the total pressure exerted is equal to the partial pressure of each gas.




Ptotal= Pa+Pb+Pc...




Pa= Ptotal * molar fraction of a.




molar fraction of a= Moles of gas a/ Total moles of gas.

Henry's law

Look it up




[A]= kH (henry constant)* Partial pressure A.




and in case of changing pressure




A1/P1=A2/P2




- pay attention to use MOLAR VALUE for A's not moles (aka divide moles by volume).

vapor pressure

pressure exerted by the evaporated molecules on the surface of the liquid.

Graham's law of diffusion and effusion

movement of molecules from high concentrations to low concentrations.

If a gas particles travel at the SAME average kinetic energy, what does that mean....especially if one is faster.




hint* according to KE= 1/2 MV^2*

since they both have the same KE, then the one traveling faster MUST be less in mass (ligher).

Pleural effusion

fluid flows into the pleural space through small openings in the capillaries or lymphatic vessels. This causes pressure to build up around the lungs which hinders breathing.

Deviation of the Ideal Gas Law




(Due to pressure).

1- at moderately high pressure, a gas' volume would be less than that predicted by the gas law.


2-At extremely high pressure, The gas molecule's size becomes large relative to the distance between them causing them to have a larger volume than that predicted by the ideal gas law.




for example, the ideal gas law assumes that a gas can be compressed to take up a zero volume; this is not possible because gas particles have volume themselves.

Deviations of the ideal gas law due to temperature.

AS temperature goes down, the intermolecular forces causes molecules to attract. the attraction causes the volume to be less than predicted by the Ideal gas law,

The closer a gas gets to its boiling point, the less ideally it acts. True or False.f

True.

Van Der Waals Equation of STATE

it is a correction to the IDEAL GAS LAW EQUATION.




Look it up on page 271.

The kinetic molecular theory

summary for the chapter theories.