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9 Cards in this Set

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What is the relationship between wavelength (m) and frequency (Hz)?

λv = c




where c = velocity of light = 3.00 x 10^8 ms^-1


and λ = wavelength

If a sodium flame emits at 589.6 nm, what is the frequency of this electromagnetic radiation?

(nm = 1 x 10^-9)
λv = c


v = c/λ = 3.00 x 10^8 ms^-1 / 5.89 x 10^-7 m


= 5.09 x 10^14 Hz


= 5.09 THz

Planck: The energy of a quantum (photon) is given by the equation...?

E = hv




where h = Planck's constant, 6.63 x 10^-34 Js

What is the value of Planck's constant?

6.63 x 10^-34 Js

Electrons and electromagnetic waves exhibit properties of both waves and particles.




Suggest evidence which indicates that electromagnetic radiation has particle properties.

The photoelectric effect
- the ejection of electrons from a material on irradiation (exposure of radiation) of light. Photons carry the energy from Planck's Law with a current only flowing above a minimum frequency.

The photoelectric effect


- the ejection of electrons from a material on irradiation (exposure of radiation) of light. Photons carry the energy from Planck's Law with a current only flowing above a minimum frequency.



Electrons and electromagnetic waves exhibit properties of both waves and particles.




Suggest evidence which indicates that electromagnetic radiation has wave properties.

Interference or diffraction or refraction.

Interference or diffraction or refraction.

Electrons and electromagnetic waves exhibit properties of both waves and particles.




Suggest evidence which indicates that electrons have wave properties.

Electron diffraction.

Electron diffraction.

De Broglie pointed out that the energies calculated for a wave and for a particle must be equal for anything that was behaving as both.



What is the equation he used to show this?

λ = h/p




Where: λ = wavelength of wave


p = momentum of particle (i.e. mass x velocity)


h = Planck's constant (6.63 x 10^-34 Js)




The de Broglie Relationship links together wave (λ) and particle (p) properties. This explains the so called 'wave-particle duality'.

Early ideas treated the electrons in an atom like planets going round the sun. The path was a well-defined ORBIT. Now that we know that an electron has wave-like properties, with a wavelength (λ) the same order of magnitude as the size of an atom - such precision is impossible. All we can do is to determine the probability than an electron is in a certain place.




Which principle is this referring to?

THE UNCERTAINTY PRINCIPLE (established in 1927 by Heisenberg).