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46 Cards in this Set
- Front
- Back
Alteration of texture
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loss of solubility
tougher or softer |
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Alteration of flavor
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off flavors from lipid oxidation
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Alteration of nutritive value
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loss of vitamins over long term storage
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Alteration of color
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browning reactions
enzymatic or maillard |
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Alteration of safety
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toxic substances formed or helpful substances formed
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Reactions leading to deterioration of food quality or safety
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Non-enzymatic browning
Enzymatic browning Oxidation Hydrolysis Metal interactions Lipid isomerization Lipid cyclization Lipid oxidation-polymerization Protein denaturation Protein cross linking |
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Product factors governing stability of foods
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chemical properties of individual constituents
oxygen pH water activity Glass transition Wg |
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Environmental factors governing stability of foods
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Temperature
time Composition of atmosphere chemical, physical, biological treatments exposure to light contamination physical abuse |
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how can food scientists help society
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good food supply
cost of food health of food food regulations resolve controversies about food: GMOs, hormones |
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why is water important
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in every food product
solvent in processes heat transfer medium allows reactions to occur influences sensory affects storage |
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water comparing to other compounds
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High
melting point heat capacity surface tension heat of phase transitions low density normal viscosity |
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water can hydrogen bond to ___ water molecules
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4
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how much are hydrogen bonds affected in thawing ice
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about 15% of H bonds disrupted
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How do large ions affect fluidity of water
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large ions interrupt the structure, making the water more fluid
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how do small ions affect fluidity of water
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small ions make the water come together, the water is less fluid
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hydrophobic interactions
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hydrocarbon groups with other hydrocarbons in order to get away from polar water
means less surface area is by the water |
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water binding
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tendency of water to associate with hydrophilic substances
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bound water
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water not removed from food
not a solvent |
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water-holding capacity
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ability of a matrix of molecules to trap large amounts of water
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hydrophobic interaction
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non-polar groups go together to avoid interaction with polar water
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water activity
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vapor pressure of solvent above sample
----------------------------------------------------------- vapor pressure of pure water at same temperature |
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when is vapor pressure a bad indicator of stability
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when present with solutes, look at ability of microbe to grow in food with the solute
temperature changes prep by adsorption |
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molecular mobility
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translational or rotational motion of molecules
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when is molecular mobility useful to predict stability
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proton transfer
radical recombination acid-base reactions enzyme-catalyzed protein folding polymer chain growth |
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when is molecular mobility not useful for stability
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small molecules
growth of vegetative microbes |
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use of molecular mobility in food
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starchy foods
boiled confections protein based foods dried, frozen, freeze-dried foods |
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temperature of glass transition
Tg |
temperature at which a supersaturated solution converts to a glass
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glass
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substance that is an amorphous (noncrystalline) solid
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multilayered water
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finishes first-layer available sites
H bonds to neighboring water molecules plasticizing action on solutes |
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bulk phase water
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freezable
large increase on molecular mobility decrease in viscosity increase rates of reactions |
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hysteresis
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adding water back to a sample that has already been dried
not superimposeable on an isotherm prepared by desorption |
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2 types of dispersions
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change in particle size
change in arrangement of particles |
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change in particle size
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dissolve/grow
ostwald ripening coalescence-particles come together |
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change in arrangement of particles
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aggregation/peptization
sedimentation move farther or closer apart in a large group sink or float |
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causes of deaggregation of aggregated particles
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lowers osmotic pressure
lowers ionic strength enhances solvent quality changes temperature changes pH shear forces |
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Polymer gels
covalent cross links |
can be flexible or stiff
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polymer gels
microcrystallites |
noncovalent
salt bridges |
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particle gels
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when structures attract at random
cluster to cluster |
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ostwald ripening
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growth of large particles in a dispersion at expense of small ones
leads to disappearance of small particles |
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creaming
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dispersed particles move upward
opposite of sedimentation |
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Bancroft's rule
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emulsion of water, oil, surfactant
continuous phase becomes one in which surfactant is most soluble |
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emulsion formation
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intense agitation to disrupt droplets
emulsifier transported to new surface area |
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partial coalescence
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parts of particles associate but never fully come together
triacylglycerol crystals |
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3 main types of instability of foams
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ostwalt ripening
drainage of a liquid through foam layer coalescence of bubbles due to instability of film between them |
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emulsions
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dispersions of one liquid in another
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foam formation
supersaturation |
gas is dissolved in the liquid at high pressure. When the pressure is released, gas bubbles form.
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