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11 Cards in this Set

  • Front
  • Back

Electrochemical cell

1. Generate electricity


2. Cathode: is positively charged (reduction)


3. Anode: is negatively charged (oxidation)


4. Electrodes cannot be inert

Electrolytic cell

1. A battery is needed


2. Anode: is positively charged (attracts anions, oxidation)


3. Cathode: is negatively charged (attracts cations, reduction)


4. Electrodes can be inert

inert electrodes

Carbon, platinum

Factors affecting what is discharged

1. Types of electrodes


2. Concentration of electrolyte (>electrochemical series)


3. State of electrolyte: Molten/Aqueous?


4. Reactivity/electrochemical series


- more reactive, more easily ionized


- more inert, more easily discharged

Electrochemical series for anions

SO4


NO3


Cl


Br


I


OH

Bond forming

- H

Bond breaking

+H

Endothermic delta H

positive

Exothermic delta H

negative

Endo example

1. most decomposition reaction


2. C, CO, H2 reduces metal oxides


3. 2NH4Cl(s) +Ba(OH)2•8H2O(s) → BaCl2(s) +2NH3(g) +10H2O(l)


4. hydrolysis

Exo example

1. most combination reaction


2. combustion


3. neutralisation


4. most double replacement


5. metal + acid


6. metal + water