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24 Cards in this Set

  • Front
  • Back

lowest heat of hydrogenation per mole

most stable structure

which of following has the highest melting point?


a) trans-2-butene


b) cis-2-butene


c) n-butane


d) 1-propanol


e) 1-pentanol

e) 1-pentanol




melting point is determined by intermolecular attraction, weight, and geometry

can PhOCHCH2 form H-bond with water?
Yes - due to O

H2 / CaCO3 / Pd

hydrogenation of the alkyne with a poisoned metal catalysts


--> SYN addition of H2 --> (Z) alkene

positron emission

---> 1e

electron capture

-1e --->

beta decay

---> -1B

electron is excited when...

the energy of incident electromagnetic radiation is equal to the energy of the transition

alkali metal reacts violently with water to form...

hydroxide (ex. KOH etc)

increasing the temperature almost always increases the rate of reaction because...
more molecules have sufficient energy to react

(inc in temp increases the average kinetic energy)

Which of the following factors does not influence the rate constant?




a) the frequency of collisions


b) the temperature


c) a catalyst


d) the heat of reaction


e) the structure of the reactants

d) the heat of reaction



the heat of reaction involves the energy of the products, which does not affect the rate constant


Charge for PO4


-3

active metal

so reactive that they are found in nature only in cationic form

NO2 ---> NH2
H2, Pt or Sn HCl

Ph-OH ---> Ph-Cl

SOCl2 or PCl3

Ph-Cl ---> Ph-CH3

(CH3)2CuLi, ether

D-Sugar

CH2OH group (6 carbon) is above the plane of the ring

hemiacetal group in sugar

the molecule can open up to its free aldehyde group --> reducing sugar




+ tollen test


+ benedicts test



sucrose

glucose -- fructose



no hemiacetal group at C1 --> non reducing sugar


no mutarotation

reducing sugar

1) hemiacetal group at C1


2) mutarotation


3) open up to free aldehyde group --> + tollen test

non reducing sugar

1) acetal group at C1


2) no mutarotation


3) - tollen and benedict test

CH3CO3H / H3O+
anti addition to alkene

Front (Term)

Back (Definition)


Ephesians 3:20