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33 Cards in this Set

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Dalton

Measured the masses of reactants and products.



Proposed atoms.



Atoms are never created or destroyed.

1803

Thompson

Deflected particles is cathode ray tube.



Atoms have + & - charges.



Negative charge = electrons.



Plum Pudding Atom Model.

1897

Millikan

Used oil drops in an electric field of known strength to find charge-to - masses ratio of electrons.

Random guy that no one on YouTube talks about

Rutherford

Fired alpha particles through gold foil.



Measured the scatter patterns and found that the atoms were deflected by the foil.



The mass of the atom is concentrated at the center and the rest of it is mostly empty space.

1909

Planck

Electromagnetic energy is quantization (composed of bundles).



E=hv


OR


E=hc/wavelength

Bohr

Electrons have fixed radius.



Electrons with higher energy are further from center.



Bohr model (planetary model) only accurate for atoms with 1 electron.



Electrons with more energy give off more electromagnetic radiation.



Quantum leaps: electrons jump energy levels.

1913

de Broglie

Identified wave characteristics of matter by combining E=mc^2 and E=hv.



All particles have a wave nature.

Heisenberg

It is impossible to know both the position and momentum of the electron at the same time.



We need a wave model to understand electron behavior.

Schrodinger

Attributed a wave function to electrons.



The wave function describes where an electron might exist. High probability areas are called orbitals.



This is called the Electron Cloud Model

Orbital Types

s, p, d, f

Atomic Mass

Mass of protons + mass of neutrons

Atomic Number

Total nuclear charge



# of protons

Isotopes

Atoms with same # of protons but different # of nuetrons.



Carbon-12 and Carbon-14

Average Mass Number du(atomic weight) (molar mass)

Takes into account the frequencies of different isotopes



Molar Mass: the mass in grams of 1 mole of atoms.



6.02 × 10^23 atoms = 1 mole



Atomic weight is closest in value to the most common isotope.

Electrons

Three ways to locate electrons. (Quantum numbers, orbital notation, electron configurations)

Pauli Exclusion Principle

No 2 electrons can occupy the same energy level or have the same set of 4 quantum numbers.

Quantum Numbers

Used to locate electrons.


There are four of them.



Distance from nucleus


Type of orbital filled


Orientation of the orbital


Spin direction of electron

Orbital Notation

Identifies location and parallel spin of electron.

Electron Configurations

Identify the # of electrons in each type of orbital at each energy level.

Aufbau Principle

Electrons exist first at the lowest energy level until something g excites them.

Hund's Rule

Electrons enter orbitals of equal energy singly with the same spin before they become paired.

Principal Quantum Number (n)

Represents the shell / energy levels. Aka: distance from the nucleus.



Possible values of 1-7


Angular Momentum Quantum Number (l)

Represents the subshell or orbital type.



When n=1, l=0 (s orbital)


When n=2, l=0 or 1 (s, p)


When n=3, l= 0,1, or 2 (s, p, d)


When n=4, l= 0, 1, 2, or 3 (s, p, d, f)

Magnetic Quantum Number (m1)

Represents the orbital position.



When l=0, m1=0 (1 s orbital)


When l=1, m1= -1, 0, 1 (3 p orbitals)


When l=2, m1= -2, -1, 0, 1, 2 (5 d orbitals)


When l=3, m1= -3, -2, -1, 0, 1, 2, 3 (7 f orbitals)



Orbital with the most negative # is filled first.

Magnetic Spin Quantum Number

Each orbital can contain 2 elections.



1 electron has a positive spin, 1 has a negative spin.



The first electron always has a positive spin.

Diamagnetic Elements

Have a paired electron in each orbital. "Stable"



All subshells are filled and are not affected by magnetic fields.

Paramagnetic Elements

Have an unpaired electron in at least one orbital.



The unpaired electron creates a magnetic field that responds to external magnetic fields.

Atomic Radii

Size of the atom

Ionization Energy

Energy required to remove an electron from the atom

Electron Affinity

How much an atom wants to gain an electron


Electronegativity

Ability of an atom to hold tightly to an atom

Ionic Attractions

Combination of metal and non-metal



Difference in electronegativity greater than or equal to 1.7



Electron leaves the less electronegativity atom and creates a positive charge. When it joins the other atom, a negative charge is formed.



The two atoms are now attracted to eachother.



Bond, ionic bond. Electrons taken, not shared.

Covalent Bonds

Occur between non-metals



Electromagnetic difference between 0 and 1.7.



Electrons are shared



# of possible covalent Bonds = 8 - group # of the element.