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54 Cards in this Set
- Front
- Back
What is the most important thing to describe concerning the behavior of the electron?
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Energy |
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Each quantum number has a...
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Restriction |
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If two symbols are in the same orbital, they have....
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Two opposite spins
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These type of orbitals are orbitals with the same energy |
Degenerate
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The water skull electrons involved in chemical bonding
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Valence Electrons
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When elements have the same number of electrons they are... |
Iso-electronic |
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Occurs when one made of a substance forms its settlements when they are in their most standard state |
Enthalpy Chhange |
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The notation used to introduce which orbital e- is occupying |
l-value |
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Defines the shape of the electron cloud, which are called orbitals |
Electron cloud |
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Are spherical in shape so they have only one orientation |
S-orbitals
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S-orbitals are spherical in shape so they have
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one orientation
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P-Orbitals have a dumbell shape and have... |
3 orientations
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have a dumbell shape and have 3 orientations
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P-Orbitals |
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Can be used to describe the behavior of the of the e- in a atom |
Quantum Number
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Atoms _________in size going across the periodic table |
Decrease |
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Atoms____in seize going down the periodic table |
Increase |
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The effective nuclear charge_______ going across the periodic table |
Increases |
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The energy required to move an electron from an atom or ion |
Ionization Energy |
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What does Hund's rule says what? |
That electrons enter the orbitals singly before they are paired up in a degenerate set of orbitals |
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The size of the atoms depends on what? |
The number of electrons
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Cations are ________ than corresponding neutral atoms |
Smallere |
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Atoms are _____larger than corresponding neutral atoms
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Larger |
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What is the effective nuclear charge equation? |
Z-S |
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Is the minimum energy required to remove an e- from a gaseous atom or ion |
Ionization Enegry |
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All Ionization energies are endothermic or exothermic?
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Enothermic |
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Ionization energies ________ going across a perdiod |
increase |
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The first infinity for oxygen is ___(exo or indo) and the second is ____( exo or indo) |
exothermic and indothermic |
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Hydrogen and Helium have what type of rule? |
Noble Gas Rule |
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Depends on the size and the charges of that are involeved |
Lattice Ennegry |
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Lewis Dot Structures= |
Molecules |
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Lewis Dot Symbol= |
Atoms |
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The water molecule has ________bonds and __________
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2 single covalent bonds and 2 lone paris |
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Dividing the atoms up into 2 is called the |
Formal Charge
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What element is the most electromagnetic?
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Flourine |
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When Nitrogen has ______bonds it will not have any lone pairs, so its formal charge will be what? |
4; +1 |
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When oxygen has _____ bonds and _______ lone pairs the formal charge is what? |
2;2; and 0 |
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Must have 8e- if you have less you are violating what rule? |
The Octet Rule |
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Berilium is hypervalent or hypovalent? |
Hypovalent |
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The sum of formal charge =
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the charge of the ion |
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A type of bond that occurs in metals and is based upon the sea of electron metal |
Metallic Bonds |
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The strength of the ionic bond depends upon 3 factors: |
The size of ions involved The charge of the ions Lattice Energy |
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What elements will not violate the octet rule? |
Carbon, Nitrogen, Oxygen, and Flournine
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In copounds where ________ form _____ covalent bonds, they will never violate the octet rule |
CL, Br, and I Single |
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When oxyegen has __ bonds and __ lone pair its formal charge is +1
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3 and 1 |
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The best structure is usually the one with the... |
Lowest formal charge |
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Elements in period 3 and higher may have an ______ and is said to be _________ |
Expanded octet; hypervalent |
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If an element is not satisfied with its electrons than it is said to be hypervalent or hypovalent? |
Hypovalent |
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Nitrogen will always have a formal charge of _____ when it has 4 bonds |
+1 |
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Is defined as the energy required to break one mole of the bond into a gas phase
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Bond Energy |
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As bond energy increase.... bond length does what? |
Decrease |
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An estimate of the molecular geometry can be mad by using the what? |
VSEPR |
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What does VSEPR stand for? |
Valence Shell Electron Pair Reputation Theory |
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If the central atom does not have any lone-pairs, than the molecular geometry will be the _____ as the electronic geometry. |
Same |
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j |
j |