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47 Cards in this Set

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  • Back
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How many electrons in each shell / energy level?

2, 8, 8

A compound formed from a metal and a nonmetal consists of ___

Ions.


The metal atoms lose electrons to form positive ions, and the nonmetal atoms gain electrons to form negative ions. The opposite charges mean they're strongly attracted.

The limestone cycle

CaCO3 --HEAT--> CaO + CO2


CaO + H2O ---> Ca(OH)2 + HEAT


Ca(OH)2 + CO2 ---> CaCO3

Uses of calcium hydroxide Ca(OH)2

An alkali that can be used to neutralize acidic soils in fields, faster than powdered limestone.


Adding water forms limewater (aq)


Tests for the presence of carbon dioxide; it turns cloudy when carbon dioxide is bubbled through it because calcium carbonate is being formed.

Uses of powdered limestone

Powdered limestone can be heated in a kiln with powdered clay to make cement.


Cement + water --> mortar*


Cement + aggregate --> concrete



*used for sticking bricks together

Advantages of limestone quarrying

+limestone is widely available and cheap


+also easy to cut


+hard-wearing but attractive


+concrete is a cheap and easy way of constructing buildings


+limestone, concrete, and cement don't rot and are fire resistant


+concrete doesn't corrode

Disadvantages of limestone quarrying

-Quarrying leaves ugly, permanent holes


-the process (inc. explosions) creates noise and dust


-waste material produces tips


-lots of dust from cement factories causes breathing problems


-energy needed is likely to come from burning fossil fuels

Reduction

When an ore is reduced oxygen in removed by adding carbon to it, however this only works with metals lower than carbon on the reactivity series (less reactive)

Electrolysis

Electrolysis is the breaking down of a substance using electricity.


It requires a liquid to conduct the electricity, called the electrolyte. The electrolyte has free ions - these conduct the electricity.


Electrons are taken away by the positive anode and given away by the negative cathode.


As ions lose or gain electrons they become atoms or molecules and are released.

Displacement

If you put a reactive metal into a dissolved metal compound, the reactive metal will bond more strongly to the nonmetal part of the compound, and pushes out the less reactive metal.


Eg, copper sulfate + iron --> iron sulfate + copper


+scrap iron is cheap and copper is quite expensive

Bioleaching

Bacteria gets energy from the bond between copper and sulfur, separating the copper from the ore in the process. The leachate (solution produced) contains copper which can be extracted by filtering.

Phytomining

When plants are grown in soil that contains copper, the copper gradually builds up in the leaves because the plants can't use it. The plants can be harvested, dried and burned in a furnace, and the copper can be collected from the ash leftover.

Advantages of mining ores

+useful products can be made


+provides the local area with jobs and money

Disadvantages of mining ores

-causes noise


-scars the landscape


-loss of habitats


-deep mine shafts can be dangerous



-mining/extracting uses a lot of energy, mainly from burning fossil fuels


-important to conserve finite fossil fuels


-burning fossil fuels also contributes to acid rain, global dimming and climate change

Advantages of recycling metals


(No disadvantages)

+uses a fraction of energy used to mine/extract them


money


+conserves finite resources


+consequently saves money +conserves finite resources +reduces waste for landfills, which take up space and pollute the surroundings


+reduces waste for landfills, which take up space and pollute the surroundings


General properties of metals

•strong (hard to break) but can be bent or hammered into different shapes


•great at conducting heat


•conduct electricity well

Properties of copper

•good conductor of electricity


•hard and strong but can be bent


•doesn't react with water



Ideal for electrical wires

Properties of aluminium

•corrosion-resistant


•low-density


•pure aluminium isn't very strong, but forms hard, strong alloys



Used in transportation and packaging

Properties of titanium

•corrosion-resistant


•low density


•very strong



Used in aerospace industry (eg, airframes and engines) because of lightweight, strength, and ability to withstand high temperatures

Metal corrosion

Some metals corrode when exposed to air or water, so they need to be protected. If they corrode, they lose their strength and hardness.

Metal fatigue

When metals are repeatedly stressed/strained over time, metal fatigue leads to them breaking , which can be very dangerous (eg, in planes)

Alloys

Different elements have different sized atoms, so when an atom such as carbon is added to pure iron, the smaller carbon atoms will change the layers of pure iron atoms, making it more difficult for them to slide over each other, making alloys harder.

Alloys of iron (steel)

Low carbon steel = easily shaped, used in car bodies


High carbon steel = hard + inflexible, used for cutting tools (blades) + bridges


Stainless steel (with chromium and sometimes nickel) = corrosion-resistant, used in cutlery and containers for corrosive substances

Electrolysis to purify copper

The cathode starts as a thin piece of pure copper


The anode is a large amount of impure copper, which will dissolve


Electrons are taken away from copper atoms at the anode, causing them to go into the solution as Cu(2+) ions.


Cu(2+) ions near the cathode gain electrons and turn back into copper atoms


The impurities are dropped off at the anode as a sludge, whilst pure copper atoms bond to the cathode, which builds into a thicker piece of pure copper

What is the electrolyte (definition + common examples)

A liquid to conduct the electricity



Often metal salt solutions from the ore (copper sulfate)


Or molten metal oxides

Anode / cathode

Electrons are taken away by the positive anode and given away by the negative cathode


Cath(y) is dead so in the negative world


Anny is alive (positive world)

Anode = positive


Cathode = negative

Displacement reaction

If you put a reactive metal into a solution of dissolved metal compound, the more reactive metal will bond more strongly to the non metal part of the compound and pushes out the less reactive metal

Bioleaching + phytomining vs traditional methods of extraction

Traditional methods are quite damaging to the environment


These methods have a smaller impact, but they're slower

Bioleaching

Bacteria gets energy from the bond between copper and sulfur, separating the copper from the ore in the process. The leachate (solution produced) contains copper, which can be extracted (eg) by filtering

Phytomining

Growing plants in soil that contains copper. The plants can't use or get rid of the copper so it gradually builds up in the leaves. The plants are harvested, dried and burned in a furnace. Copper can be collected from the ash left in the furnace

Why use bioleaching / phytomining

The supply of copper-rich ores is limited, so it's important to recycle as much copper as possible


Demand for it is high, may lead to shortages. Extract from low grade ores / or from waste produced when copper is extracted

Metal extraction (+) (-)

+useful products can be made


+provides local people with jobs, brings money to the area, services (health, transport) can be improved


-noise


-scarring of the landscape


-loss of habitats


-deep mine shafts can be dangerous for a long time after they've been abandoned

Recycling metals

Mining / extracting requires a lot of energy, mostly from fossil fuels. Fossil fuels are running out, important to conserve them. Burning them contributes to acid rain, global dimming, global warming


Recycling metals only uses a fraction of the energy needed to mine / extract new metal. Energy costs, so recycling saves money


Finite amount of each metal in Earth, so they need to be conserved


Reduces amount send to landfill (takes up space + pollutes surroundings)

Properties of most metals

•strong (hard to break) but can be hammered or bent into different shapes


•great at conducting heat


•conduct electricity well

Uses of Metals

Strength + 'bend ability' -> bridges, car bodies. Something heat needs to travel through, eg, saucepan base


Conductivity -> electrical wires

Especially transition metals

Copper

Good conductor of electricity (electrical wires)


Hard + strong but can be bent


Doesn't react with water

Aluminium

Corrosion resistant


Low density


Isn't particularly strong, but forms hard, strong alloys

Aeroplane (strong, bendable, light)

Titanium

Low density


Very strong


Corrosion resistant

Replacement hips (doesn't corrode, very strong, light weight)

Metal flaws

Metals are useful structural materials, but some corrode when exposed to air and water, so they need to be protected (eg, painting)


Metal fatigue (repeated stresses + strains) -> metals breaking = dangerous (eg, in planes)

Iron from blast furnace

Only 96% iron (rest is impurities like carbon). Used as cast iron. Ornamental railings, but not much else bc it's too brittle.

What happens to iron from blast furnace

All the impurities are removed. This pure iron has a regular arrangement of identical atoms, which makes the iron soft and easily shaped.


Too bendy for most uses.

Purified

Alloys of iron

LC steel = easily shaped -> car bodies HC steel = very hard, inflexible, -> blades for cutting tools, bridges


Stainless steel (+chromium, nickel) = corrosion resistant -> cutlery, containers for corrosive substances

Steels

Why are alloys harder than pure metals

Different elements have different sized atoms. When carbon is added to pure iron, the smaller carbon atoms with disrupt the layers of pure iron atoms, making it more difficult for them to slide over each other

Crude oil is a mixture of hydrocarbons

No chemical bonds between different parts of the mixture, so all the different hydrocarbon molecules aren't chemically bonded to each other = all keep original properties (eg, condensing points)

Properties of a mixture

Are just a mixture of the properties of the separate parts

The shorter the molecules...

Less viscous


More volatile (lower boiling point)


More flammable

Uses of hydrocarbons depend on their properties

Volatility - refinery gas fraction has lowest boiling point, so is used as bottled gas.


Petrol = higher boiling point. Liquid (ideal for storing in fuel tank) flows to the engine where vaporized


Most viscous -> lubricating engine parts and covering roads