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29 Cards in this Set

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Colloid
a mixture whose particles are intermediate in size between those of a suspension and a solution (1 – 100 nm)
i. Cloudy when concentrated, clear when dilute
ii. Exhibit Tyndall effect (scattering light)
iii. Exhibit Brownian motion (chaotic movement of particles)
Hydrogen bond
a relatively strong intermolecular force in which a hydrogen atom that is covalently bonded to a very electronegative atom is also weakly bonded to an unshared electron pair of another electronegative atom in the same molecule or one nearby
brownian motion
the chaotic movement of colloidal particles, caused by collision with particles of the solvent in which they are dispersed
deliquescent
a term describing a substance that removes sufficient water from the air to form a solution; the solution formed has a lower vapor pressure than that of the water in the air (remove enough water from air to dissolve)
desiccant
a hygroscopic substance used as a drying agent (ex. silica gel)
effloresce
to lose water of hydration; the process occurs when the hydrate has a vapor pressure higher than that of water vapor in the air
electrolyte
a compound that conducts an electric current in aqueous solution or in the molten state; all ionic compounds are electrolytes, but most covalent (molecular) compounds are not
emulsion
the colloidal dispersion of one liquid in another
b. Emulsifying agent necessary for forming/maintaining stability
c. Examples:
i. Soap emulsifies oil in water
ii. Egg yolks emulsify oil and vinegar to make mayonnaise
hygroscopic
a term describing salts and other compounds that remove moisture from the air
suspension
a mixture form which some of the particles settle out slowly upon standing (particles are greater than 100 nm)
tyndall effect
scattering of light by particles in a colloid or suspension, which causes a beam of light to become visible
hydrate
a compound that contains water of hydration (water of hydration – water molecule that are part of a crystal structure); this entire crystalline structure (including water molecules) is called the hydrate
miscible
describes liquids that dissolve in each other
saturated (solution)
a solution containing the maximum amount of solute for a given amount of solvent at a constant temperature and pressure; an equilibrium exists between undissolved solute and ions in solution
activation energy
minimum energy colliding particles must have in order to react
Catalyst
a substance that increases the rate of reaction by lowering the activation-energy barrier; the catalyst is not used up
entropy
a measure of the disorder of a system; systems tend to go from a state of order (low entropy) to a state of maximum disorder (high entropy)
free energy
the energy available to do work (Can be obtained from reactions that actually occur)
amphoteric
substance that can act as both an acid and a base; water is amphoteric
Solution
stable, homogeneous mixture, particles are less than 1nm
Describe how temperature and pressure can effect the solubility of a solute
Increased temperature increases the frequency and force of collisions.
a. For solids dissolved in liquids, solubility usually increases with increasing temp
b. For gases dissolved in liquids, solubility decreases with increasing temp
c. Solubility of gases increases with increased pressure above gas
Collision theory
Atoms, ions, and molecules can react to form products when they collide, provided that the particles have enough kinetic energy. Particles lacking the necessary kinetic energy to react bounce apart when they collide. Activation energy is the minimum amount of energy particles must have to react.
Arrhenius acids
compounds that ionize to yield hydrogen ions in aqueous solution
Arrhenius bases
compounds that ionize to yield hydroxide ions in aqueous solution
BL acid
hydrogen-ion donor
BL base
hydrogen-ion acceptor
Lewis acid
Substance that can accept a pair of electrons to form covalent bond
Lewis base
Substance that can donate a pair of electrons to form covalent bond
Strong/weak acids and bases
Strong acids are completely ionized in aqueous solutions. (dissociate completely)
Weak acids ionize only slightly in aqueous solutions.
Strong dissociate completely in water; weak don't