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49 Cards in this Set
- Front
- Back
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Rate Law |
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Reverse rate |
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K >>>>> 1 |
Product Favored |
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K <<<<<< 1 |
Reactant favored |
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Pressure constant |
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Hess' Law |
Each step of a single reaction has its own K |
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Hess' Law |
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Hess' Law |
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ICE Chart ****WATCH FOR MOLAR MASSES**** |
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Reaction Quotient For a rxn NOT at EQ |
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Q > K |
Reverse rxn favored R > P |
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Q < K |
Forward reaction favored R < P |
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Q = K |
Reaction is at equillibrium |
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Heterogeneous Equillibrium |
Rs or Ps are in more than one phase |
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SOLIDS and LIQUIDS are NOT in Kc |
Their concentrations don't matter |
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Haber Process |
Produces amonia (NH4) Iron catalyst @high temp and pressure |
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LeChatlier: Change in [CONCENTRATION] |
Rxn shifts to consume excess |
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LeChatlier: Change in pressure (volume) |
Rxn shifts to reduce the mols of gas |
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LeChatlier: Change in temp |
increase T = decrease Kp |
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Catalyst |
Increase both fwd and rev rxns |
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Arrhenius Acid |
Increases [H+] |
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Arrhenius Base |
Substance that increases [OH-] |
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BronLowry Acid |
Proton donor |
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BronLowry Base |
Proton acceptor |
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Lewis Acid |
Electron pair acceptor |
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Lewis Base |
Electron pair donor ***same as BronLowry*** |
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Amphiprotic |
Can be acid or base H2O |
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Conjugates |
CONJ ARE WEAK IF STRONG ACID/BASE |
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HCl |
SA |
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HBr |
SA |
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HI |
SA |
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HNO3 |
SA |
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HClO3 |
SA |
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HClO4 |
SA |
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H2SO4 |
SA |
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STRONG Bases |
NaOH KOH Ca(OH)2 Sr(OH)2 Ba(OH)2 |
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Kw = [H+] * [OH-] |
1*10^-14 |
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Percent ionization |
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Ka and Kb |
Big Ka means ACIDIC Big Kb means BASIC |
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If Kc in seperate steps are >10^3 apart, IGNORE 2ND K |
Polyprotic acids |
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Cation rxn w H2O |
Acidic |
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Anion rxn w H2O |
Basic |
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Increasing acid strength |
Increase polarity Weaker H-X bond Increased stability of conjugate bond |
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Binary acids |
Members of a group |
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Binary trends |
Bond strength. Dec as go down table Acid strength. Inc as go up and R Acidity. Inc w electronegativity |
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Oxyacids |
Y-O-H O inc electronegativity |
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Carboxylic |
Resonance STABALIZES base and increases acidity |
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Reverse rxn |
1/K |
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2x (rxn) |
K^2 |