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49 Cards in this Set

  • Front
  • Back

Rate Law

Reverse rate

K >>>>> 1

Product Favored

K <<<<<< 1

Reactant favored

Pressure constant

Hess' Law

Each step of a single reaction has its own K

Hess' Law

Hess' Law

ICE Chart



****WATCH FOR MOLAR MASSES****

Reaction Quotient



For a rxn NOT at EQ

Q > K

Reverse rxn favored


R > P

Q < K

Forward reaction favored


R < P

Q = K

Reaction is at equillibrium

Heterogeneous Equillibrium

Rs or Ps are in more than one phase

SOLIDS and LIQUIDS are NOT in Kc

Their concentrations don't matter

Haber Process

Produces amonia (NH4)


Iron catalyst


@high temp and pressure

LeChatlier:


Change in [CONCENTRATION]

Rxn shifts to consume excess

LeChatlier:


Change in pressure (volume)

Rxn shifts to reduce the mols of gas

LeChatlier:


Change in temp

increase T = decrease Kp

Catalyst

Increase both fwd and rev rxns

Arrhenius Acid

Increases [H+]

Arrhenius Base

Substance that increases [OH-]

BronLowry Acid

Proton donor

BronLowry Base

Proton acceptor

Lewis Acid

Electron pair acceptor

Lewis Base

Electron pair donor ***same as BronLowry***

Amphiprotic

Can be acid or base



H2O

Conjugates

CONJ ARE WEAK IF STRONG ACID/BASE

HCl

SA

HBr

SA

HI

SA

HNO3

SA

HClO3

SA

HClO4

SA

H2SO4

SA

STRONG Bases

NaOH


KOH


Ca(OH)2


Sr(OH)2


Ba(OH)2

Kw = [H+] * [OH-]

1*10^-14

Percent ionization

Ka and Kb

Big Ka means ACIDIC


Big Kb means BASIC

If Kc in seperate steps are >10^3 apart, IGNORE 2ND K

Polyprotic acids

Cation rxn w H2O

Acidic

Anion rxn w H2O

Basic

Increasing acid strength

Increase polarity


Weaker H-X bond


Increased stability of conjugate bond

Binary acids

Members of a group

Binary trends

Bond strength. Dec as go down table


Acid strength. Inc as go up and R


Acidity. Inc w electronegativity

Oxyacids

Y-O-H



O inc electronegativity

Carboxylic

Resonance STABALIZES base and increases acidity

Reverse rxn

1/K

2x (rxn)

K^2