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63 Cards in this Set

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What is the definition of Endothermic?

The system gains heat from its surroundings and the surroundings cool down

What is the definition of Specific Heat Capacity

The amount of energy required to raise the temperature of 1g of a substance by 1°c

What is the definition for Enthalpy?

The heat gained or lost by a system at constant pressure

What is the definition for Exothermic

The system loses hear to its surroundings and the surroundings heat up

What is the definition for Energy?

A measure of ability to do work or create heat

What is the definition of Heat?

The energy transferred between two objects as a result of a difference in temperature between them

What is the definition of Calorimetry?

The measurement of the heat flow in or out of a system

State the law of conservation of energy.

Energy is neither created or destroyed; the sum total of energy in the universe remains constant

What is the q value for an Endothermic Reaction?

+

What is the ∆H value of an Endothermic Reaction?

+

What is the q value for an Exothermic Reaction?

-

What is the ∆H value of an Exothermic Reaction?

-

How would you calculate the quantity of Heat flow?

q=mC∆T

How do you find ∆T?

Final temperature-initial temperature

How do you calculate Enthalpy?

∆H=n•∆Hfus or ∆H=n•∆Hvap

Where do you find the value of ∆Hfus or ∆Hvap?

On the table called "Heat of Physical Change"

How are the heat values for a system and its surroundings related?

Equal magnitude, opposite signs

How would you figure out how much heat is released when 75.0 g of water reacts with sodium by the following reaction? 2Na(s)+2H2O(l)➡150kJ+H2+2NaOH(aq)

Turn grams to moles: 75.0gh2o•1mol/18.02g=4.16molh2o Turn moles to kJ: 4.16molh2o•150kJ/2molh2o=312kJ

How would you draw a heating curve for bromine heated from 20°c to 900°c and label the portions of the curve that represent ∆Hfusion, ∆Hvaporization, qgas, qliquid, qsolid? Melting point =97.8°. Boiling point=883°c

How do you calculate how much energy is required to heat 20.0g of mercury from -35°c to 500°c

How would you calculate the heat if 0.175 mol of NaOH(s) is dissolved in water? NaOH➡Na+(aq)+OH-(aq) ∆H= -445.1kJ/mol

∆H=n•∆Hsol


=(0.175mol)(-445.1kJ/mol)


=-77.89kJ

State Hess' Law

If you add two or more thermochemistry equations to get a final equation, you can add the heats of the reaction to get a final heat of reaction

How do you calculate ∆H for the following equation:


C2H4(g)+Cl2(g)➡C2H3Cl(g)+HCl(g)

How do you calculate ∆H for reactions using standard heats of formation?

∆H=∆Hprod-∆Hreact

What are four factors that affect the rate of a chemical reaction? Explain each what factor does that affects reaction rate.

Temperature- Increases rate of collisions(more particle movement increase collision and more effective)


Catalyst- Lowers activation energy


Concentration- more particles causes more collisions


Smaller Particles- size makes more particles available to react

State "le Châtelier's Principle"

If a system in dynamic equilibrium is disturbed, it will react to reach a new equilibrium

How do you calculate the equilibrium constant for the following raction

What is the common ion effect?

Lowering of the solubility of a salt due to the addition of a common ion

What is a spontaneous reaction?

Naturally occurring reaction that favours the products, releases energy

What is a non-spontaneous reaction?

A reaction that doesn't produce significant product at equilibrium

What is entropy?

Measurement of disorder in a system

What is an Arrhenius acid?

Compound that ionize to produce hydrogen ions

What is an Arrhenius base?

Compound that ionize to produce hydroxide ion

What is a Bronsted-Lowry acid?

Hydrogen ion donor

What is a Bronsted-Lowry base?

Hydrogen ion acceptor

What is a Lewis acid?

Accepts a pair of electrons during a reaction

What is a Lewis base?

Donates a pair of electrons during a reaction

How to get pH from [H+]

pH=-log[H+]

[H+] to [OH-]

[OH-]=kW/[H+]

[OH-] to [H+]

[H+]=kW/[OH-]

[OH-] to pOH

pOH=-log[OH-]

pH to pOH

pOH=14-pH

pH to [H+]

[H+]=10^-pH

What is a Hydroxide ion?

Water molecule that loses a hydrogen ion

What is a polyprotic substance?

Have the ability to lose or gain more than one proton

What is a buffer?

Maintains a nearly constant pH when diluted or when a strong acid or base is added

What are strong acids

100% dissociation when dissolved in water

What is a Hydronium ion?

Water molecule that gains a hydrogen ion

What are weak acids?

Less than 100% dissociation when dissolved in water

What is the pH scale?

A way to express the hydrogen ion concentration

List two properties of acids and two properties of bases

Acids- sour taste, conducts electricity, and neutralise bases


Base- bitter taste, conducts electricity, neutralise acids, and feels slippery

What is an amphiprotic substance?

A substance that can be a Bronsted-Lowry acid or a Bronsted-Lowry base depending on the situation

Which way will the 50% be eating?

The acid or base higher on the chart

What is a neutralisation reaction?

When a reaction between an acid and base produce water and a salt

What a sketch of a base with an acid looks like

What a sketch of a curve of an acid with a base

How do indicators work?

A substance that is one colour when it gains a proton and another when it loses a proton

What is the equation for Ka?

What concentration would you use to find concentration or volume?

C1V1=C2V2