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28 Cards in this Set

  • Front
  • Back

Solutions

Homogeneous mixtures of two or more pure substances

Solute-solute interaction

Must be overcome to disperse particles when making a solution

Solvent-solvent interactions

Must be overcome to make room for the solute

Solvent-solute interactions

Like dissolves like


Stronger the interaction, greater solubility of a solute in that solvent

Crystallization

Opposite of solution making processcfeq

Saturated Solution

Rate of opposing processes is equal, additional solute will not dissolve unless some crystallizes from solution

Unsaturated Solution

Any amount of solute less than the ma amount dissolved in solution

Solubility

Max amount of solid that can dissolve in a given amount of solvent at a given temperature

Supersaturated solutions

Solvent holds more solute than is normally possible at that temperature.


Are unstable

Miscible

Liquids that mix in all proportions

Immiscible

Liquids that do not mix in one another

Henry's Law

Solubility of a gas is proportional to the partial presur of the gas above the solution

Most solids, temp increase

Solubility increases

All gases, temp increases

Solubility decreases

Ppm

(Mass of componetnt/ total mass of solution)* 10^6

Colligative properties

Depends on quantity only, not identity


-vapor pressure lowering


-boiling point elevation


-freezing point depression


-osmotic pressure

Vapor pressure

VP of a solution is lower than that of the pure solvent

i

Takes dissociation in solution

Semipermeable membranes

Allows smaller particles to pass through, blocks larger particles

Osmosis

Net movement of solvent molecules from low to high concentration across a semipermeable membrane

Osmotic pressure

Applied pressure to stop osmosis

Isotonic Solution

Same osmotic pressure, solvent passes through membrane at same rate both ways

Hypotonic Solution

Lower osmotic presure, solvent will leave solution at a higher rate than it enters with

Hypertonic Solution

Higher osmotic presssure,


Solvent will enter at higher rate than it leaves with

Crenation

Red blood cells in a hypertonic solution,


Shrivel as water leaves

Hemolysis

Red blood cells, if stored in a hypertonic solution, burst

Colloids

Suspensions of particles larger than individual ions or molecules but too small to be settles out by gravity

Tyndall Effect

Colloidal suspension can scatter rays of light