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55 Cards in this Set

  • Front
  • Back
Chemistry
science of stuff
chemical rxn
any process that turns one substance into another

substance A---substance B
matter
composed of many types of atoms
scientific method
observation, hypothesis, experiment
theory
tested hypothesis that tells why things happen

serves to explain
natural law
summary of observed behavior
law of conservation of mass
total mass of materials is not affected by a chemical change in those materials
measurement
quantitative observation, number and scale
mass
measure of resistance of an oject to change its state of motion
force necessary to give object acceleration
weight
response of mass to gravity
1 liter
1 cm^3
L---cm----ml
(1 dm)^3
1 mL
1000cm= 1000mL
law of conservation of mass
(lavoisier)
mass is neither created nor destroyed
law of definite proportions
(proust)
a given compund contains the same proportion of elements by mass

CuCO3 --5.3:4:1 ratio of Cu, O2, and C
law of multiple proportions
when 2 elements form a series of compounds the ratio of the masses of the 2nd element to 1 gram of the 1st can always be reduced to whole #'s
electrons
discovered by J.J. Thompson with a cathode ray

mass: 9.11 10^-31 kg
Berzelius
said to respresent elements based on alphabetical name

Carbon-C, Calcium-Ca, Iron (ferrum)-Fe
scientific law
generalization form observations
E=mc^2
energy= (associated mass change) x (speed of light)^2
Atom
"no cut"
1. smallest entities in a bulk sample that have chem. properties of the sample
2. atoms are identical, in element
3. atoms of different elements differ
4. atoms aren't created or destroyed in chem rxn and their mass doesn't change
5.compounds= joining atoms of the element of which they are composed
law of constant composition
doesn't matter how, when, where substance is prepared, won't effect elemental composition
mercury
as discovered by Torricelli
mercury is both a barometer (measures pressure)
and an altimeter (measures height, as the levels of mercury change according to height
atmospheric pressure
mass of air being pulled toward the center of the earth by gravity--weight of the air
unit conversion of pressure
atm, mmHg, torr, pa
1 atm= 760 mmHG= 760 torr = 101, 325 Pa
Ideal gas law
PV= nRT
Boyle's law
P1V1=P2V2

V is proportional to 1/p
Charles's law
V1/T1=V2/T2

v is directly proportional to T
Avogadro's law
V1/n1=V2/n2

v is proportional to n at constant temp ad pressure
STP
standard temperature ad pressure

0C and 1 atm
molar mass
g/mol

=dRT/P
mol
m/molar mass
Dalton's Law of partial pressures
Ptotal= P1 +P2 +P3
= ntotal (RT/V)
mole fraction
X1= (n1/ntotal) = (P1/Ptotal)
effusion
passage of gas through a tiny hole in an evacuated chamber
diffusion
mixing of gases
real gas behavior
behave ideally at high temp and low pressure
must consider particle interactions and volumes
moles
things to remember:
1 mole= atomic mass of element
ex. 1 mole of Carbon= 12.01 g
6.022 X10^23 atoms= 1 mole
getting molar mass
ex. molar mass of CH4
1 x 12.01 g C
4 x 1.008 g H
____________
16.04 g = 1 mole of CH4
Kinetic theory of gases
1. atoms and molecules obey Newton's law of motion
2. gas molecules don't exert forces on each other
3. gas molecules interact w/ container walls only when they hit them
4. collisions are elastic
5. ignore shape and size of gas molecules
6. motion is random
Newton's Law of motion
1.An object in motion stays in motion (and continues in straight line unless acted on by force), and object at rest stays at rest
2. change in motion, caused by force, happens i the same direction the force is acting and is inversely proportional to the mass of the object
3. every action has an equal and opposite reaction
momentum
mass x acceleration
KE=
2/3 RT
temperature
number that scales the KE of motions of molecules in a sample of matter (measuring energy)
energy
number you can attribute to physical system that tells you how much work needs to be done in the future
heat capacity
amount of energy needed to be put in a system to make substance's temperature rise 1K
mass percent
mass of each element in 1 mole of compound compared to total mass of 1 mole of compund

1. obtain molar mass of compound and indiv. elements
2. MM ratio of element versus compound x 100%
empirical formula
percent to mass
mass to mole
divide by small
multiply by whole
molecular formula (using EF)
1.take molar mass of EF
2.divide molecule weight of compound by molar mass of EF
3.multiply resulting whole number to EF
molecular formula
1. percent to mass
2. mass X molar mass of compound
3. molar mass of element and compound to mol
significant figures
1. non-zero digits always
2. any zeros between 2 sig. figs
3. a final zero or trailing zeros in the decimal point
rounding off
1. #<4 ---- drop it
2. #>5 -----increase proceeding # by 1
3. #=5-----make proceeding # even (zero is even)
electrolysis
coined by Faraday
separating chemically bonded elements and compounds by running electric current through them
stoichiometry
1. balance equation
2. mass to moles
3. moles of known to unknown substance using mole ratio
4. convert from moles back to grams if necessary
limiting reactants
1. convert g-->mol (to make sure the moles are in terms of the rest of the substances)
---OR--
2. mol ratio ( compare moles in equation to moles they give you)
percent yield
actual yield
_____________
theoretical yield X100%
theoretical yield
amount product formed when limiting reactant is completely consumed