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19 Cards in this Set

  • Front
  • Back

thermodynamics

heat and other forms of energy

thermochemistry

heat absorbed or evolved by a chemical reaction

energy

potential or capacity to move matter


-electromagnetic


-mechanical


-electrical


-chemical

kinetic energy

energy based off motion

potential energy

energy based off position ( in a field of force)


ex: gravitational, electrical, magnetic

internal energy, u

kinetic and potential energy of particles that make up substance

heat capacity, C

of a sample of substance


-quantity of heat needed to raise the temperature of the sample of substance by 1 degree C (or Kelvin)


Molar Heat Capacity

Heat capacity for 1 mol of substance

Specific Heat Capacity, s

AKA specific heat


- Quantity of heat needed to raise the temperature of one gram, of substance by 1 degree C (or K) at constant pressure


-using: heat capacity

manipulating a thermochemical egn.

-when the eqn. is multiplied by a factor, the value of change H must also be multiplied by it


-when a chem. eqn is reversed

thermochemical equation

chem. eqn. for a reaction


- include phase labels and enthalpy of reaction after eqn.

Law of conservation of energy

energy may be converted from one form to another, but total energy remains constant


-2 parts: Thermodynamic system and surroundings

Heat, q

-energy that flows into or out of system


(is Temp. differential) due to a diff. in temp. between system + surroundings. high--->low

endothermic

q (+) heat is absorbed by system.


-applied to reaction, system, beaker etc.

exothermic

q (-) heat is evolved by system

Heat of Reaction

(specific value)


-value of q required to return a system to the given temp. at completion of reaction

Heat of Reaction

(specific value)


-value of q required to return a system to the given temp. at completion of reaction

Enthalpy, H

Extensive Property (dependent on how much you have) used to obtain heat absorbed/ evolved in a chem. reaction

state function

property of system that depends only on present state