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97 Cards in this Set
- Front
- Back
Solution
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A homogeneous misture in which the molecules or ions of the components freely intermingle
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Solvent
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The medium into which the solutes are mixed or dissolved
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Aqueous Solutions
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A solution in which the solute is dissolved in water
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Solute
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Any substance dissolved in the solvent
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Concentration
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The ratio of the amount of solute either to the amount of solvent or to the amount of solution
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Percentage Composition
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The amount of solute per amount of solution- solute to solution ratio
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Dilute Solution
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When the ratio of solute to solvent is small
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Concentrated Solution
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When the ratio of solute to solvent is large
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Solution
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A homogeneous mixture in which the molecules or ions of the components freely intermingle
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Solvent
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The medium into which the solutes are dissolved
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Aqueous Solutions
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Solutions in which the solute is dissolved in water
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Solute
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Any substance that is dissolved in the solvent
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Concentration
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The ratio of the amount of solute either to the amount of solvent or to the amount of solution
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Percentage Concentration
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A solute to solution ratio
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Dilute Solution
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When the ratio of solute to solvent is small
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Concentrated Solution
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When the ratio of solute to solvent is large
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Saturated Solution
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When the amount of solute that can dissolve in a given amount of solvent reaches its limit at a given temperature
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Solubility
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The amount required to give a saturated solution
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Unsaturated Solution
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A solution having less solute than required for saturation
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Supersaturated Solution
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When a solution actually contains more solute than required for saturation; are unstable
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Precipitate
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A solid that forms in a solution
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Precipitation Reaction
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A chemical reaction that produces a precipitate
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Electrolytes
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Electrically conducting aqueous solutions
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Dissociation
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When an ionic compound dissolves in water and the ions separate from each other and enter the solution as more or less independent particles that are surrounded by molecules of the solvent
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Strong Electrolytes
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Strong conductors of electricity; salts
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Nonelectrolytes
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Aqueous solutions of most molecular compounds; do not conduct electricity
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Hydrated
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When a particle is surrounded by water molecules in the solution
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Molecular Equation
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When all the formulas are written with the ions together, as if the substances in solution consist of neutral molecules
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Ionic Equation
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When the formulas are written so that the formulas of all soluble strong electrolytes are dissociated
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Spectator Ions
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Ions that do not actually take part in a reaction
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Net Ionic Equation
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Same as the ionic equation; however, the spectator ions are eliminated
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Material Balance
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One of the criteria for balanced ionic and net ionic equations; there must be the same number of atoms of each kind on both sides of the arrow
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Electrical Balance
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One of the criteria for balanced ionic and net ionic equations; the net electrical charge on the left must equal the net electrical charge on the right (although this charge does not necessarily have to be zero)
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Acids
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Have a tart or sour taste; a substance that reacts with water to produce the hydronium ion
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Bases
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Have a somewhat bitter taste and have a soapy feel; substances that produce hydroxide ions in water
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Salt
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Any ionic compound that doesn't contain either a hydroxide ion or an oxide ion
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Ionization Reaction
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Ions form where none existed before
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Monoprotic Acids
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The molecules HCl and HC2H3O2; capable of furnishing only on H+ per molecule of acid
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Polyprotic Acids
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Can furnish more than one H+ per molecule
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Diprotic Acid
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Has two successive steps to ionize
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Triprotic Acids
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Have three successive steps to ionize
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Acidic Anhydrates
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Oxides that react to form molecular acids containing hyrdrogen, which are then able to undergo reaction with water to yield a hydronium ion; anhydrate means without water
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Basic Anhydrates
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Soluble metal oxides; react with water to form the hydroxide ion as one of the products
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Strong Acids
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Strong electrolytes
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Chemical Equilibrium or Dynamic Equilibrium
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When two opposing reactions occur at the same rate
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Position of Equilibrium
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The extent to which the forward reaction proceeds toward completion
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Binary Acids
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The binary compounds of hydrogen with many of the nonmetals; in aqueous solutions
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Oxoacids
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Acids that contain hydrogen, oxygen, and another element
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Molar concentration/Molarity
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The number of moles of solute per liter of solution
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Qualitative Analysis
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When it is determined which substances are present in a sample without measuring their amounts
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Quantitative Analysis
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The goal is to measure the amounts of the various substances in a sample
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Oxidation-Reduction Reactions
(Redox Reactions) |
Electron transfer reactions
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Oxidation
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The loss of electrons by one reactant
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Reduction
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The gain of electrons
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Oxidizing Agent
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The substance that accepts the electrons
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Reducing Agent
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The substance that supplies the electrons
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Skeleton Equation
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Shows only the ions (or sometimes molecules, too) involved in the redox changes.
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Nonoxidizing Acids
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Acids that have poor oxidizing abilities
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Corrosion/Tarnishing
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When metals react directly with oxygen
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Energy
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Something an object has if the object is able to do work
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Kinetic Energy
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The energy an object has when it is moving
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Potential Energy
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Energy an object has that can be changed to kinetic energy; can be thought of as stored energy
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Chemical Energy
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The potential energy of chemicals
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Law of the Conservation of Energy
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Energy cannot be created or destroyed; it can only be changed from one form to another
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Heat (Thermal Energy)
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Energy that is transferred between objects caused by differences in their temperatures
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Thermal Equilibrium
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When a system and its surroundings come to equal temperatures
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Internal Energy (E)
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The sum of energies for all of the individual particles in a sample of matter
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Molecular Kinetic Energy
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The energy associated with the movement of particles within matter
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Internal Energy Change
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The change in internal energy that accompanies both chemical and physical changes
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Kinetic Molecular Theory
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Temperature is related to the average kinetic energy of the atoms and molecules of an object
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State
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The complete list of properties that specify an object's current condition; includes the object's pressure, temperature, volume, anc chemical compostion (numbers of moles of all substances present)
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State Function
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Any property that, like energy, depends only on an object's current state
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Open System
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A system that can gain or lose mass and energy across its boundaries
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Closed System
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A system that can absorb or release energy, but not mass, across the boundary
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Isolated System
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A system that cannot exhange matter or energy with their surroundings
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Adiabatic
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Processes that occur within an isolated system
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Heat Capacity
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The amount of energy needed to raise the temperature of an object by 1 degree Celsius
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Specific Heat Capacity
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The amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius
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Exothermic
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Any reaction in which heat is a product
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Endothermic
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Reactions that consume energy
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Heat of Reaction
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The amount of heat absorbed or released in a chemical reaction
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Calorimetry
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The science of using a calorimeter for determining heats of reaction
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Pressure
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The amount of force acting on a unit of area; the ratio of force to area
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Atmospheric Pressure
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The pressure exerted by the mixture of gases in our atmosphere
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Expansion Work
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The energy transferred as work when a system expands or contracts against the pressure exerted by the surroundings
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Heat of Combustion
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Heat produced by a combustion reaction
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Heat of Reaction at Constant Volume
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The heat of reaction measured in a bomb calorimeter
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Heat of Reaction at Constant Pressure
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The heat of reaction in an open system
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Enthalpy
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The heat content of a system
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Enthalpy Change
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The difference in enthalpy between the initial state and the final state form some change
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Standard Heat of Reaction
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The value of the enthalpy change fro a reaction occurring under standard conditions and involving the actual numbers of moles specified by the coefficients of the equation
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Thermochemical Equation
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An equation that also shows the value of the standard heat of reaction
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Enthalpy Diagram
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A graphical construction that shows the energy relationships among the alternative pathways for the same overall reaction
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Hess's Law of Heat Summation
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The value of the standard heat of reaction for any reaction that can be written in steps equals the sum of the values of the standard heat of reaction of each of the individual steps
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Standard Heat of Combustion
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The amount of heat released when one mole of a fuel substance is completely burned in pure oxygen gas, with all reactants and products brought to 25 degrees Celsius and 1 bar of pressure
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Standard Enthalpy of Formation (Standard Heat of Formation)
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The amount of heat absorbed or evolved when specifically one mole of the substance is formed at 25 degrees Celsius and 1 bar from its elements in their standard states
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Standard State
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An element is in its standard state when it is at 25 degrees Celsius and 1 bar and in its most stable form and physical state
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