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97 Cards in this Set

  • Front
  • Back
Solution
A homogeneous misture in which the molecules or ions of the components freely intermingle
Solvent
The medium into which the solutes are mixed or dissolved
Aqueous Solutions
A solution in which the solute is dissolved in water
Solute
Any substance dissolved in the solvent
Concentration
The ratio of the amount of solute either to the amount of solvent or to the amount of solution
Percentage Composition
The amount of solute per amount of solution- solute to solution ratio
Dilute Solution
When the ratio of solute to solvent is small
Concentrated Solution
When the ratio of solute to solvent is large
Solution
A homogeneous mixture in which the molecules or ions of the components freely intermingle
Solvent
The medium into which the solutes are dissolved
Aqueous Solutions
Solutions in which the solute is dissolved in water
Solute
Any substance that is dissolved in the solvent
Concentration
The ratio of the amount of solute either to the amount of solvent or to the amount of solution
Percentage Concentration
A solute to solution ratio
Dilute Solution
When the ratio of solute to solvent is small
Concentrated Solution
When the ratio of solute to solvent is large
Saturated Solution
When the amount of solute that can dissolve in a given amount of solvent reaches its limit at a given temperature
Solubility
The amount required to give a saturated solution
Unsaturated Solution
A solution having less solute than required for saturation
Supersaturated Solution
When a solution actually contains more solute than required for saturation; are unstable
Precipitate
A solid that forms in a solution
Precipitation Reaction
A chemical reaction that produces a precipitate
Electrolytes
Electrically conducting aqueous solutions
Dissociation
When an ionic compound dissolves in water and the ions separate from each other and enter the solution as more or less independent particles that are surrounded by molecules of the solvent
Strong Electrolytes
Strong conductors of electricity; salts
Nonelectrolytes
Aqueous solutions of most molecular compounds; do not conduct electricity
Hydrated
When a particle is surrounded by water molecules in the solution
Molecular Equation
When all the formulas are written with the ions together, as if the substances in solution consist of neutral molecules
Ionic Equation
When the formulas are written so that the formulas of all soluble strong electrolytes are dissociated
Spectator Ions
Ions that do not actually take part in a reaction
Net Ionic Equation
Same as the ionic equation; however, the spectator ions are eliminated
Material Balance
One of the criteria for balanced ionic and net ionic equations; there must be the same number of atoms of each kind on both sides of the arrow
Electrical Balance
One of the criteria for balanced ionic and net ionic equations; the net electrical charge on the left must equal the net electrical charge on the right (although this charge does not necessarily have to be zero)
Acids
Have a tart or sour taste; a substance that reacts with water to produce the hydronium ion
Bases
Have a somewhat bitter taste and have a soapy feel; substances that produce hydroxide ions in water
Salt
Any ionic compound that doesn't contain either a hydroxide ion or an oxide ion
Ionization Reaction
Ions form where none existed before
Monoprotic Acids
The molecules HCl and HC2H3O2; capable of furnishing only on H+ per molecule of acid
Polyprotic Acids
Can furnish more than one H+ per molecule
Diprotic Acid
Has two successive steps to ionize
Triprotic Acids
Have three successive steps to ionize
Acidic Anhydrates
Oxides that react to form molecular acids containing hyrdrogen, which are then able to undergo reaction with water to yield a hydronium ion; anhydrate means without water
Basic Anhydrates
Soluble metal oxides; react with water to form the hydroxide ion as one of the products
Strong Acids
Strong electrolytes
Chemical Equilibrium or Dynamic Equilibrium
When two opposing reactions occur at the same rate
Position of Equilibrium
The extent to which the forward reaction proceeds toward completion
Binary Acids
The binary compounds of hydrogen with many of the nonmetals; in aqueous solutions
Oxoacids
Acids that contain hydrogen, oxygen, and another element
Molar concentration/Molarity
The number of moles of solute per liter of solution
Qualitative Analysis
When it is determined which substances are present in a sample without measuring their amounts
Quantitative Analysis
The goal is to measure the amounts of the various substances in a sample
Oxidation-Reduction Reactions
(Redox Reactions)
Electron transfer reactions
Oxidation
The loss of electrons by one reactant
Reduction
The gain of electrons
Oxidizing Agent
The substance that accepts the electrons
Reducing Agent
The substance that supplies the electrons
Skeleton Equation
Shows only the ions (or sometimes molecules, too) involved in the redox changes.
Nonoxidizing Acids
Acids that have poor oxidizing abilities
Corrosion/Tarnishing
When metals react directly with oxygen
Energy
Something an object has if the object is able to do work
Kinetic Energy
The energy an object has when it is moving
Potential Energy
Energy an object has that can be changed to kinetic energy; can be thought of as stored energy
Chemical Energy
The potential energy of chemicals
Law of the Conservation of Energy
Energy cannot be created or destroyed; it can only be changed from one form to another
Heat (Thermal Energy)
Energy that is transferred between objects caused by differences in their temperatures
Thermal Equilibrium
When a system and its surroundings come to equal temperatures
Internal Energy (E)
The sum of energies for all of the individual particles in a sample of matter
Molecular Kinetic Energy
The energy associated with the movement of particles within matter
Internal Energy Change
The change in internal energy that accompanies both chemical and physical changes
Kinetic Molecular Theory
Temperature is related to the average kinetic energy of the atoms and molecules of an object
State
The complete list of properties that specify an object's current condition; includes the object's pressure, temperature, volume, anc chemical compostion (numbers of moles of all substances present)
State Function
Any property that, like energy, depends only on an object's current state
Open System
A system that can gain or lose mass and energy across its boundaries
Closed System
A system that can absorb or release energy, but not mass, across the boundary
Isolated System
A system that cannot exhange matter or energy with their surroundings
Adiabatic
Processes that occur within an isolated system
Heat Capacity
The amount of energy needed to raise the temperature of an object by 1 degree Celsius
Specific Heat Capacity
The amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius
Exothermic
Any reaction in which heat is a product
Endothermic
Reactions that consume energy
Heat of Reaction
The amount of heat absorbed or released in a chemical reaction
Calorimetry
The science of using a calorimeter for determining heats of reaction
Pressure
The amount of force acting on a unit of area; the ratio of force to area
Atmospheric Pressure
The pressure exerted by the mixture of gases in our atmosphere
Expansion Work
The energy transferred as work when a system expands or contracts against the pressure exerted by the surroundings
Heat of Combustion
Heat produced by a combustion reaction
Heat of Reaction at Constant Volume
The heat of reaction measured in a bomb calorimeter
Heat of Reaction at Constant Pressure
The heat of reaction in an open system
Enthalpy
The heat content of a system
Enthalpy Change
The difference in enthalpy between the initial state and the final state form some change
Standard Heat of Reaction
The value of the enthalpy change fro a reaction occurring under standard conditions and involving the actual numbers of moles specified by the coefficients of the equation
Thermochemical Equation
An equation that also shows the value of the standard heat of reaction
Enthalpy Diagram
A graphical construction that shows the energy relationships among the alternative pathways for the same overall reaction
Hess's Law of Heat Summation
The value of the standard heat of reaction for any reaction that can be written in steps equals the sum of the values of the standard heat of reaction of each of the individual steps
Standard Heat of Combustion
The amount of heat released when one mole of a fuel substance is completely burned in pure oxygen gas, with all reactants and products brought to 25 degrees Celsius and 1 bar of pressure
Standard Enthalpy of Formation (Standard Heat of Formation)
The amount of heat absorbed or evolved when specifically one mole of the substance is formed at 25 degrees Celsius and 1 bar from its elements in their standard states
Standard State
An element is in its standard state when it is at 25 degrees Celsius and 1 bar and in its most stable form and physical state