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36 Cards in this Set

  • Front
  • Back
Trends in Atomic Radius
As you go down and to the left the atomic radius gets bigger.
Largest radius is in bottom lefthand corner.
Trends in effective nuclear charge (Zeff)
as you move to the right, effective nuclear charge increases,
paramagnetic
When electrons are unpaired
diamagnetic
When electrons are paired.
relationship between cations and atoms.
cations (+) are much smaller than their respective atoms
relationship between anions and atoms.
anions (-) are significantly larger than their atom.
Ionization Energy (IE)
The energy needed to to remove an electron from the atom or ion in the gaseous state.
Trends in First Ionization Energy
As you move to the right and up the IE increases, making the uppper right hand corner the highest IE.
Electron Affinity
the energy change associated with the gaining of an electron by the atom in the gaseous state. Is usually negative because it is releasing energy when it gains an electron.
generally gets more negative and exothermic as you move to the right of the PT
Metallic Character Trends
As you move to the left and down the metallic character increases. Making the lower left hand corner the most mettalic.
Hydridization for linear
sp
Hydridization for trigonal Planar
sp 2
Hydridization for tetrahedral
sp 3
Hydridization for trigoanl bipyramidal
sp3d
Hydridization for octahedral
sp3d2
Which hybridization has left over P orbitals?
sp2
Coulomb's law
2 alike charged particles tend to repel , different charged particles attract
Octet rule exceptions
odd electrons
incomplete octets: Be and B
Expanded octets: Thirds period or below
Shielding
tendency for the core electrons to shield out electrons from nuclear charge
Penetration
Ability of electrons in outer orbitals to penetrate into the region occupied by core electrons-experiences full nuclear charge
What electrons lose S electrons to make D electrons half fulled?
Cr, Cu, Mo, Ag
Are bonds breaking negative or positive?
Positive-endothermic
Are bonds forming negative or positive?
Negative-exothermic
2 e groups
2 bonding
0 lone pairs
e-linear
m-linear
3 e groups
3 bonding
0 lone pairs
e-trigonal planar
m-trigonal planar
3 e groups
2 bonding
1 lone pairs
e-trigonal planar
m-bent
4 e groups
4 bonding
0 lone pairs
e-Tetrahedral
m-tetrahedral
4 e groups
3 bonding
1 lone pairs
e- tetrahedral
m-trigonal pyramidal
4 e groups
2 bonding
2 lone pairs
e- tetrahedral
m-bent
5 e groups
5 bonding
0 lone pairs
e- trigonal bipyramidal
m- trigonal bipyramidal
5 e groups
4 bonding
1 lone pairs
e-trigonal bipyramidal
m- seesaw
5 e groups
3 bonding
2 lone pairs
e- trigonal bipyramidal
m-t-shaped
5 e groups
2 bonding
3 lone pairs
e- trigonal bipyramidal
m-linear
6 e groups
6 bonding
0 lone pairs
e-octahedral
m-octahedral
6 e groups
5 bonding
1 lone pairs
e- octahedral
m-square pyramidal
6 e groups
4 bonding
2 lone pairs
e- octahedral
m- square planar