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60 Cards in this Set
- Front
- Back
- 3rd side (hint)
Solid (Shape & Volume) |
Shape: Tightly packed Volume: Fixed |
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Liquid (Shape & Volume) |
Shape: close together Volume: shape of container |
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Gas (Shape & Volume) |
Shape: free space between particles |
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Phase of material that is typically the densest |
Solid |
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Phase of material that is most compressible |
Gas |
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Ionic Bonds |
Transfer of electrons |
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Covalent Bonds |
Sharing of electrons |
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IMFs are most important in what phases? |
Solids and Liquids |
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IMFs (increase/decrease) with distance? |
Decrease |
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Strongest IMFs |
Ion-Dipole |
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___ of the ion & ____ of the charge affect how strong the interaction is in Ion-Dipole IMFs |
Size & Magnitude |
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Increased ion charge (increases/decreases) the strength of the interaction |
Increases |
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Increased ion size (increases/decreases) the strength of the interaction |
Decreases |
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Molecules that are (polar/nonpolar) have a permanent dipole moment |
Polar |
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What determines the magnitude of the dipole moment and thus the strength of the IMFs? |
Atoms |
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Hydrogen Bonding |
H covalently bonded to F, O, and N. |
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What leads to highly concentrated partial charges with F, O, N, and H atoms? |
Large difference in electronegativity and the small sizes of F, O, and N |
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Which IMFs get stronger with increasing molecular size? |
Dispersion forces |
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Cohesion |
Between molecules of the same substance |
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Adhesion |
Between different substances |
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Viscosity |
Measure of flow |
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Phase change of Solid --> Liquid; Energy added or removed? |
Melting; Added |
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Phase change of liquid --> gas; energy added or removed? |
Vaporization; Added |
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Phase change from gas --> liquid; energy added or removed? |
Condensation; Removed |
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Phase change if liquid --> solid; energy added or removed? |
Freezing; removed |
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Phase change if solid --> gas; energy added or removed? |
Sublimation; added |
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Phase change of gas --> solid; energy added or removed? |
Deposition; Removed |
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Increased surface area (increase/decrease) the rate of evaporization? |
Increase |
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Increased temperature (increase/decrease) the rate of evaporization? |
Increase |
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Why does liquid boil? |
The particles gain enough kinetic energy to completely overcome the attractive forces |
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How are gases condensed? |
By decreasing their temperature or increasing the pressure |
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The greater the IMFs between molecules the (more/less) energy needed to vaporize? |
More |
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The greater the IMFs the (faster/slower) rate of evaporization? |
Slower |
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Molecules in the vapor state can (gain/lose) energy though the collisions with other molecules? |
Lose |
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The (greater/less) the IMFs, the (greater/less) energy is needed for the vapor molecules to condense? |
Greater; Less |
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Volatile |
Liquids that evaporate easily |
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Is salt water volatile or nonvolatile? |
Nonvolatile |
Think of the ocean, does it evaporate easily? |
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Equilibrium vapor pressure |
Rate of evaporation = rate of condensation |
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At a given temperature is vapor pressure independent or dependent of IMFs? |
Depends on IMFs |
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Phase changes |
. |
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Clausis-Clapeyron Equation |
ln (P2/P1) = -delta Hvap/ R (1/T2 - 1/T1) |
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Solute |
Gets dissolved |
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Solvent |
Does the dissolving |
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Solution |
Homogeneous mixture |
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Endothermic |
+ delta H soln |
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Entropy |
Measure of a system's disorder or dispersal of particles throughout a system. Energy tends to disperse throughout the system |
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Where is it saturated, unsaturated, and supersaturated? |
Saturated - on the line, Unsaturated - below the line, Supersat - above the line |
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Molarity |
Moles solute / L solution |
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Molality |
Moles solute / kg solvent |
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Henry's Law |
Sgas = (KH)(Pgas) |
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Van't hoff factor of NaCl |
2 |
Number of pieces it breaks into |
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Van't Hoff factor of CaCl2 |
3 |
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Van't Hoff factor of NH3 |
1 (covalently bonded non metal) |
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Van't Hoff of NaOH |
2 |
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Van't Hoff of Na3PO4 |
4 |
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Van't Hoff of CH3OH |
1 (all covalently bonded) |
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Osmotic Pressure Formula |
(pie symbol) = iMRT |
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Which intermolecular forces are the weakest? |
Dispersion forces |
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What are the only things coligative properties depend on? |
Concentration of solute particles in a solution |
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Which concentration unit is temperature dependent? |
Molarity |
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