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60 Cards in this Set

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Solid (Shape & Volume)

Shape: Tightly packed


Volume: Fixed

Liquid (Shape & Volume)

Shape: close together


Volume: shape of container

Gas (Shape & Volume)

Shape: free space between particles

Phase of material that is typically the densest

Solid

Phase of material that is most compressible

Gas

Ionic Bonds

Transfer of electrons

Covalent Bonds

Sharing of electrons

IMFs are most important in what phases?

Solids and Liquids

IMFs (increase/decrease) with distance?

Decrease

Strongest IMFs

Ion-Dipole

___ of the ion & ____ of the charge affect how strong the interaction is in Ion-Dipole IMFs

Size & Magnitude

Increased ion charge (increases/decreases) the strength of the interaction

Increases

Increased ion size (increases/decreases) the strength of the interaction

Decreases

Molecules that are (polar/nonpolar) have a permanent dipole moment

Polar

What determines the magnitude of the dipole moment and thus the strength of the IMFs?

Atoms

Hydrogen Bonding

H covalently bonded to F, O, and N.

What leads to highly concentrated partial charges with F, O, N, and H atoms?

Large difference in electronegativity and the small sizes of F, O, and N

Which IMFs get stronger with increasing molecular size?

Dispersion forces

Cohesion

Between molecules of the same substance

Adhesion

Between different substances

Viscosity

Measure of flow

Phase change of Solid --> Liquid; Energy added or removed?

Melting; Added

Phase change of liquid --> gas; energy added or removed?

Vaporization; Added

Phase change from gas --> liquid; energy added or removed?

Condensation; Removed

Phase change if liquid --> solid; energy added or removed?

Freezing; removed

Phase change if solid --> gas; energy added or removed?

Sublimation; added

Phase change of gas --> solid; energy added or removed?

Deposition; Removed

Increased surface area (increase/decrease) the rate of evaporization?

Increase

Increased temperature (increase/decrease) the rate of evaporization?

Increase

Why does liquid boil?

The particles gain enough kinetic energy to completely overcome the attractive forces

How are gases condensed?

By decreasing their temperature or increasing the pressure

The greater the IMFs between molecules the (more/less) energy needed to vaporize?

More

The greater the IMFs the (faster/slower) rate of evaporization?

Slower

Molecules in the vapor state can (gain/lose) energy though the collisions with other molecules?

Lose

The (greater/less) the IMFs, the (greater/less) energy is needed for the vapor molecules to condense?

Greater; Less

Volatile

Liquids that evaporate easily

Is salt water volatile or nonvolatile?

Nonvolatile

Think of the ocean, does it evaporate easily?

Equilibrium vapor pressure

Rate of evaporation = rate of condensation

At a given temperature is vapor pressure independent or dependent of IMFs?

Depends on IMFs

Phase changes

.

Clausis-Clapeyron Equation

ln (P2/P1) = -delta Hvap/ R (1/T2 - 1/T1)

Solute

Gets dissolved

Solvent

Does the dissolving

Solution

Homogeneous mixture

Endothermic

+ delta H soln

Entropy

Measure of a system's disorder or dispersal of particles throughout a system. Energy tends to disperse throughout the system

Where is it saturated, unsaturated, and supersaturated?

Saturated - on the line, Unsaturated - below the line, Supersat - above the line

Molarity

Moles solute / L solution

Molality

Moles solute / kg solvent

Henry's Law

Sgas = (KH)(Pgas)

Van't hoff factor of NaCl

2

Number of pieces it breaks into

Van't Hoff factor of CaCl2

3

Van't Hoff factor of NH3

1 (covalently bonded non metal)

Van't Hoff of NaOH

2

Van't Hoff of Na3PO4

4

Van't Hoff of CH3OH

1 (all covalently bonded)

Osmotic Pressure Formula

(pie symbol) = iMRT

Which intermolecular forces are the weakest?

Dispersion forces

What are the only things coligative properties depend on?

Concentration of solute particles in a solution

Which concentration unit is temperature dependent?

Molarity