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59 Cards in this Set

  • Front
  • Back
Label the following: ice, liquid water, vapor water, melting point and temp, boiling point and temp, each axis,
Where are the 3 phases?
Where is the supercritical liquid?
Where are the triple and critical points?
Are polar molecules hydrophilic or hydrophobic?
hydrophilic
Are non-polar molecules hydrophilic or hydrophobic?
hydrophobic
What kind of substances are detergents?
amphipathic
The rate of evaporation in a closed container is ____ the rate of condensation.
equal to
While a pure liquid is boiling, the temperature is _____.
constant
Is evaporation endothermic or exothermic?
endothermic
Is condensation endothermic or exothermic?
exothermic
The solid to gas change of state is called ____. Is it exothermic or endothermic?
sublimation
endothermic
The solid to liquid change of state is called ____ or ____. Is it exothermic or endothermic?
melting/fusion
endothermic
The liquid to solid change of state is called ____. Is it exothermic or endothermic?
freezing
exothermic
The liquid to gas state of change is called ____. Is it exothermic or endothermic?
vaporization
endothermic
The gas to liquid state of change is called ____. Is it exothermic or endothermic?
condensation
exothermic
Which substance has the highest boiling point and why?
CH3CH2CH2CH2OH OR CH3CH2OCH2CH3
CH3CH2CH2CH2OH because of the H-bond
What is the best way to tell in a C H O chain, which one has the highest boiling point?
whichever has the higher imf's
OH in it will have higher imf's
whichever is biggest will also have higher imf's
Place the following in order of increasing imf's.
1. CH4
2. CH3CH2CH3
3. CH3CH3
1<3<2
Dispersion forces are also called ____.
London forces
The bigger the London forces the ____ the molar mass.
larger
The smaller the dispersion forces the ____ the molar mass.
smaller
Liquids have a ____ density than gases.
higher
Compared to liquids, gases have a ___ strength of imf's.
weaker
What are the four types of bonding? Put them in order of weakest to strongest.
Dispersion
Dipole-dipole
H-bond
Ion-dipole
What kind of bond force is present in mixtures of ionic compounds and polar compounds?
Ion-dipole
Polar liquids are miscible/not miscible with nonpolar liquids.
not miscible
Compared to liquids, solids have a ___ strength of imf's.
stronger
Polar liquids are miscible/not miscible with polar liquids.
miscible
What are immiscible liquids?
liquids that don't mix
If one molecule is round and another is oval shaped and they have the same molecular weight, which one has stronger dispersion forces, and why?
the oval because it has more surface contact between the molecules
The molar volume of water vapor is ____ than that of liquid water.
larger
The molar volume of liquid water is ____ than that of water vapor.
smaller
With detergents, H2O bonds to the ____ end and oil bonds to the ____ end.
hydrophilic
hydrophobic
The higher the temperature, the ____ the rate of evaporation.
faster
Liquids that evaporate easily are known as ____ liquids. List a few examples.
volatile
gasoline, fingernail polish remover
Liquids that do not evaporate easily are known as ____ liquids. List an example.
non-volatile
oil
The weaker the imf's, the ____ the rate of evaporation.
faster
Name the molecular geometries with 2 e- regions, and the degrees.
Linear
180
Name the molecular geometries with 3 e- regions, and the degrees.
trigonal planar
bent
120
Name the molecular geometries with 4 e- regions, and the degrees.
tetrahedral
trigonal pyramidal
bent
109.5
Name the molecular geometries with 5 e- regions, and the degrees.
trigonal bipyramidal
see saw
t shaped
linear
90 and 120
Name the molecular geometries with 6 e- regions, and the degrees.
octahedral
square pyramidal
square planar
90
imf's influence what three different properties?
surface tension
viscosity
capillary action
What is surface tension?
the tendancy of liquids to minimize their surface area
The stronger the surface tension would mean the imf's are ____.
stronger
What is viscosity?
the resistance of a liquid to flow
What three things does viscosity depend on?
imf's
size and shape of molecules
temperature
The stronger the imf's the ____ viscous something is.
more
____ and ____ molecules are more viscous.
larger and longer
____ and ____ molecules are less viscous.
smaller and shorter
The higher the temp the ____ viscous something is. Why?
less
more energy available to overcome imf's
In capillary action, cohesive force is ...
attractive imf's between the liquid molecules
In capillary action, adhesive force is ...
attractive imf's that occur between the liquid and the wall of the tube
Cohesive < Adhesive
capillary action
Cohesive > Adhesive
no capillary action
Intramolecular forces hold ____ together and are ____ than intermolecular forces.
atoms
stronger
Intermolecular forces hold ____ together and are ____ than intramolecular forces.
molecules
weaker
The rate of vaporization ____ with the increasing surface area.
increases
The rate of vaporization ____ with the decreasing surface area.
decreases
The gas to solid state of change is called ____. Is it exothermic or endothermic?
deposition
exothermic