Reading...
Play button
Play button
Use LEFT and RIGHT arrow keys to navigate between flashcards;
Use UP and DOWN arrow keys to flip the card;
H to show hint;
A reads text to speech;
65 Cards in this Set
- Front
- Back
|
Which of the d-block groups is different and why?
|
Group 12 because they have all their d-orbitals filled.
|
|
|
Why can d-block metals form alloys?
|
Because their radii are very similar
|
|
|
Why are the lanthanoids contracted?
|
Because the f-orbitals are bad at shielding.
|
|
|
NO ligand
|
nitrosyl
neutral |
|
|
CO ligand
|
carbonyl
neutral |
|
|
(en)
|
ethylenadiamine
neutral |
|
|
dien ligand
|
diethylenediamine
neutral |
|
|
H2O ligand
|
aqua
neutral |
|
|
NH3 ligand
|
ammine
neutral |
|
|
F ligand
|
fluoro
anionic |
|
|
Cl ligand
|
chloro
anionic |
|
|
Br
|
bromo
anionic |
|
|
I ligand
|
iodo
anionic |
|
|
OH ligand
|
hydroxo
anionic |
|
|
O2 ligand
|
oxo
anionic |
|
|
CN ligand
|
cyano
anionic |
|
|
NC ligand
|
isocyano
anionic |
|
|
NCS ligand
|
thiocyanato
anionic |
|
|
SCN ligand
|
isothiocyanato
anionic |
|
|
ONO ligand
|
nitrito
anionic |
|
|
NO2 ligand
|
nitro
anionic |
|
|
CO3 2- ligand
|
carbonato
anionic |
|
|
C2O4 2- ligand
|
oxalato (ox)
anionic |
|
|
SO4 2- ligand
|
sulfato
anionic |
|
|
What is the secondary prefix for 2?
|
bis
|
|
|
What is the secondary prefix for 3?
|
tris
|
|
|
What is the secondary prefix for 4?
|
tetrakis
|
|
|
What is the chemical formula of oxalato?
|
C2O4
|
|
|
Ionization Isomer
|
ligand/accompanying ion exchange
|
|
|
hydrate isomer
|
H2O exchanges with a regular ligand
|
|
|
linkage isomer
|
switch linking atom
|
|
|
Coordination Isomer
|
ligands are exchanged between complexes
|
|
|
electron orbitals that point away from point charges in octahedral
|
t2g orbitals
|
|
|
electron orbitals that point towards charges in octahedral
|
eg orbitals
|
|
|
ligand field splitting eq.
|
hc/lambda
|
|
|
t2g orbitals
|
xy, yz, zx
|
|
|
eg orbitals
|
z^2 and x^2-y^2
|
|
|
what are the d orbitals called when they are in a tetrahedral arrangement?
|
t2, e2
|
|
|
Strength of CN
|
Strong field ligand
|
|
|
Strength of CO
|
Strong field ligand
|
|
|
Strength of NO2
|
Strong field ligand
|
|
|
Strength of en
|
Strong field ligand
|
|
|
Strength of NH3
|
strong field ligand
|
|
|
Strength of H2O
|
Weak field ligand
|
|
|
Strength of ox
|
Weak field ligand
|
|
|
strength of OH
|
Weak field ligand
|
|
|
strength of F
|
Weak field ligand
|
|
|
Strength of SCN
|
Weak field ligand
|
|
|
strength of Cl
|
Weak field ligand
|
|
|
strength of Br
|
Weak field ligand
|
|
|
strength of I
|
Weak field ligand
|
|
|
paramagnetic
|
unpaired e-
pulled into magnetic field |
|
|
diamagnetic
|
paired e-
pushed out of magnetic field |
|
|
mass and charge of alpha particle
|
mass 4
charge 2 |
|
|
mass and charge of a beta particle
|
mass 0
charge -1 |
|
|
mass and charge of an electron
|
mass 0
charge -1 |
|
|
mass and charge of a photon (gamma ray)
|
mass 0
charge 0 |
|
|
Mass and charge of a positron (B+)
|
mass 0
charge 1 |
|
|
mass and charge of a proton
|
mass 1
charge 1 |
|
|
mass and charge of a neutron
|
mass 1
charge 0 |
|
|
freq. =
|
E/h
|
|
|
wavelength=
|
c/freq.
|
|
|
Ci=
|
3.7e10 Bq
|
|
|
half life =
|
ln2/k
|
|
|
N=
|
Noe^(-kt)
|
