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13 Cards in this Set

  • Front
  • Back

A spontaneous process occurs when

ΔGsys < 0

If ΔHsys < 0, then

ΔSsurr > 0

The standard state for temperature when thermodynamic determination are being made is

25˚C

Equilibrium is established when

ΔGsys = 0

When a certain set of kinetic data for a reaction was analyzed and plotted, a plot of 1/[A] versus t resulted in a straight line. This result indicates that

The reaction is second order.

When a certain set of kinetic data for a reaction was analyzed and plotted, a plot of [A] versus t resulted in a straight line. This result indicates that

The reaction is zeroth order.

A substance that speeds up a reaction without being consumed itself while being present in the same phase as the reacting molecules is known as

A homogenous catalyst

Catalyst

a substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change.

For a chemical reaction, the state where the concentrations of all reactants and products remain constant with time is referred to as

chemical equilibrium

The rate law for an elementary step in a reaction mechanism

Can be written from the molecularity of the elementary step.

Intermediate

A substance formed during a middle step of a chemical reaction between reactants and the desired product.

When a certain set of kinetic data for a reaction was analyzed and plotted, a plot of ln[A] versus t resulted in a straight line. This result indicates that

the reaction is first order.

A substance that speeds up a reaction without being consumed itself while being present in a different phase that the reacting molecules is known as

a heterogenous catalyst.