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14 Cards in this Set

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States of Matter


Gas State


-indefinite shape


-indefinite volume


-particles widely seperated


-particles moving rapidly

States of Matter


Liquid State

-indefinite shape


-fixed volume


-particles in close contact


-particles (or clusters of particles) can move past one another.

States of Matter


Solid State

-Fixed shape


-fixed volume


-particles in close contact


-particles vibrate around a central position

Kinetic Molecular Theory of Gases

Explains why:


-gases have very slow density


-gases are highly compressible


-gases have no definite shape of volume


-gases diffuse


-gases exert a pressure


-aersol cans explode when heated


-gases never settle


-gas particles tavel in straight lines between collisions



Pressure

-force exerted per unit of area



P=F/A



psi=lb/in2

Pressure Units

1 atmosphere (atm)= average atmospheric pressure at sea level.



1 atm= 760 mmHg


760 torr



1 torr= 1 mmHg


1 atm=29.92 inHg

Prssure Definitions

Barometer- a device used to measure atmospheric pressure.



Manometer-a device used to measure gas pressure in a reaction vessel.

Gas Laws

-Four Properties: volume (V)


pressure (P)


temperature (T)


amount- mass or moles (n)



A gas law is a statement of an observed relationship among these four properties.

Gas Laws:


Pressure-Volume Law

Boyle's Law: Pressure-Volume Law


For a constant amount of gas at a constant temperature, the pressure of a gas is inversely proportional to the volume of its container.



As V goes up, P goes down.


P*V+constant


P1V1=constant=P2V2



P1V1=P2V2

Gas Laws:


Volume-Temperature Law

Charles's Law: Volume-Temperature Law


For a fxed (constant) amount of gas at a constant pressure, the volume of a gas is directly proportional to its absolute (Kelvin) temperature.



As T goes up, V goes up.


V=Tx constant


V/T = constant



V1/T1=V2/T2

Gas Laws:


Combined Gas Law

P1V1 P2V2


______ = ________


T1 T2



**Temperature must be in Kelvin (K).



Use this to fine the new pressure, volume, or temperature of a gas when only the amount of gas (number of moles) is constant.

Gas Laws:


Adovgadro's Hypothesis

2 Consequences of Advogradro's Hypothesis:


1) We can define a standard molar volume- the volume occupied by one mole any gas at a certain temperature and pressure.


2) we can do stoichiometry for reaction components in the gas phase using rations of volumes rather than rations of moles.

Gas Laws:


Advogradro's Hypothesis

STP=Standard Temperature and PRessure for a gas.



Standard Temperature= 0*C or 273K


Standard Pressure= 1atm or 760 torr


As STP, the volume occupied by one mole of any gas.. 22.4 L/mol (Standard Molar Volume)

Gas Laws:


Advogadro's Hypothesis

If 2 gases have the same T and P, equal volumes contain equal moles.





Says: For a gas at a constant temperature and pressure, the volume of the gas is directly proportional to the number of moles (n) of gas.



PV=nRT