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19 Cards in this Set
- Front
- Back
redox reaction
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an electron donor gives up electron to an electron acceptor (often accompanied by a hydrogen atom)
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three important electron acceptors/carriers
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NAD+ source: niacin
NADP+ FAD source: riboflavin *typically reduced |
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carbohydrate catabolism
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primary source of energy in the cell is glucose
cells break down glucose and transfer energy to ATP |
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aerobic respiration
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complete breakdown of glucose through a series of oxidation-reduction reactions that generate ATP, and in which the final electron acceptor is O2 (inorganic)
glycolysis krebs cycle ETC |
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Glycolysis
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glucose (6 carbon sugar) is split into two 3 carbon sugars
these smaller sugars are then oxidized and their remaining atoms are rearranged to form two molecules of pyruvate Net: 2 pyruvates 2 ATP (one per pyruvate) 2 NADH (one per pyruvate) |
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phosphofructokinase
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kinase (transfers phosphate groups) enzyme that phosphorylates fructose 6-phosphate in glucose to fructose-1, 6-biphosphate
allosterically inhibited for a period of time by ATP STEP 3 |
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intermediate stage
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1 pyruvate is oxidized to 1 NADH and Acetyl-CoA, 1 pyruvate releases carbon as 1 CO2
Net: 2 CO2 (one per pyruvate) 2 NADH (one per pyruvate) |
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kreb's cycle
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pyruvate is broken down further to 2CO2, 3 NADH, 1 FADH, and 1 ATP
Net: 6 NADH (3 per pyruvate) 2 FADH (1 per pyruvate) 2 ATP (1 per pyruvate) 4 CO2 (2 per pyruvate) |
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ETC
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electrons passed along a series of carrier molecules capable of redox reactions
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flavoprotein
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electrons are passed from NADH to flavoproteins in complex I of the ETC
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ubiquinone
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flavoproteins then pass electrons to an iron-sulfur compouds, then to ubiquinone, a small hydrophobic molecule (not a protein!!)
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cytochrome
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most of the remaining electron carriers between ubiquinone and oxygen
have heme group that accepts and donates electrons |
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oxygen
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final electron acceptor of the ETC, also picks up a pair of hydrogen ions from the aqueous solution, forming WATER
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conversions
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1 NADH = 3 ATP
1 FADH = 2 ATP |
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chemiosmosis
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generation of ATP as a direct result of the movement of hydrogen ions across a membrane (ion gradient)
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proton motive force
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potential energy create by an electrochemical gradient
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fermentation
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the incomplete oxidation of glucose in the absense of O2
process utilizes an organic compound as the final electron acceptor |
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alcohol fermentation
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pyruvate is converted to ethanol in two steps
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lactic acid fermentation
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pyruvate is reduced directly by NADH to for lactate as an end product with no release of CO2
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