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19 Cards in this Set

  • Front
  • Back
redox reaction
an electron donor gives up electron to an electron acceptor (often accompanied by a hydrogen atom)
three important electron acceptors/carriers
NAD+ source: niacin
NADP+
FAD source: riboflavin

*typically reduced
carbohydrate catabolism
primary source of energy in the cell is glucose

cells break down glucose and transfer energy to ATP
aerobic respiration
complete breakdown of glucose through a series of oxidation-reduction reactions that generate ATP, and in which the final electron acceptor is O2 (inorganic)

glycolysis
krebs cycle
ETC
Glycolysis
glucose (6 carbon sugar) is split into two 3 carbon sugars

these smaller sugars are then oxidized and their remaining atoms are rearranged to form two molecules of pyruvate

Net:
2 pyruvates
2 ATP (one per pyruvate)
2 NADH (one per pyruvate)
phosphofructokinase
kinase (transfers phosphate groups) enzyme that phosphorylates fructose 6-phosphate in glucose to fructose-1, 6-biphosphate

allosterically inhibited for a period of time by ATP

STEP 3
intermediate stage
1 pyruvate is oxidized to 1 NADH and Acetyl-CoA, 1 pyruvate releases carbon as 1 CO2

Net:
2 CO2 (one per pyruvate)
2 NADH (one per pyruvate)
kreb's cycle
pyruvate is broken down further to 2CO2, 3 NADH, 1 FADH, and 1 ATP

Net:
6 NADH (3 per pyruvate)
2 FADH (1 per pyruvate)
2 ATP (1 per pyruvate)
4 CO2 (2 per pyruvate)
ETC
electrons passed along a series of carrier molecules capable of redox reactions
flavoprotein
electrons are passed from NADH to flavoproteins in complex I of the ETC
ubiquinone
flavoproteins then pass electrons to an iron-sulfur compouds, then to ubiquinone, a small hydrophobic molecule (not a protein!!)
cytochrome
most of the remaining electron carriers between ubiquinone and oxygen

have heme group that accepts and donates electrons
oxygen
final electron acceptor of the ETC, also picks up a pair of hydrogen ions from the aqueous solution, forming WATER
conversions
1 NADH = 3 ATP
1 FADH = 2 ATP
chemiosmosis
generation of ATP as a direct result of the movement of hydrogen ions across a membrane (ion gradient)
proton motive force
potential energy create by an electrochemical gradient
fermentation
the incomplete oxidation of glucose in the absense of O2

process utilizes an organic compound as the final electron acceptor
alcohol fermentation
pyruvate is converted to ethanol in two steps
lactic acid fermentation
pyruvate is reduced directly by NADH to for lactate as an end product with no release of CO2