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214 Cards in this Set

  • Front
  • Back

Wood ants live in coloines of up to?

thousands of ants in a single colony

Colonies of wood ants have a mechanism to deal with threats, what is it?

To fire folic acid from their abodmens which rains down on their attackers

Some species of ants don't use it as a firing mechanism, what do they use it for instead?

Spray on themselves as a defense against microbes

Where did folic acid gets it name from?

The latin word for ant, formica

Scientists have long known chemicals play a role in?

Serveal different aspects of ant behaviour insect communication, defence and attraction of mates

Organisms are composed of?

Matter which is anything that takes up space and has mass

What is matter made up of?

Elements

What is an element?

An element is a substance that cannot be chemically broken down into a simpler form

Chemists recognize how many natural elements?

92

Each element has a symbol derived from?

Usally from the first letter or two of its name, some symbols are derived from latin or german, natrium for sodium for example

What is a compound?

A compound is a substance consisting of 2 of more different elements in a fixed ratio

Table salt for example is?

Sodium Chloride

What is pure sodium and pure chlroine?

Pure sodium is a metal and pure chlorine is a toxic gas

A compound has characteristics different from?

Those of the original elements that made it up

Define mass

Mass is the amount of matter in something where as the weight of an object is how strong gravity pulls on matter in the object

Out of the 92 elements as a % barrier, what is the boundary?

Out of the 92 elements, between 20 and 25 per cent are essential elements

There is some variation in elements?

Between organims, for example some organisms require more than another, like a human needs 25 elements and plants need 17

What 4 elements make up 96.3% of living matter?

Oxygen 65%, Carbon 18.5%, Hydrogen, 9.5% and Nitrogen 3.3%

Trace elements are reuqired in?

Small doses as they are not required in large doses, like iodine which keeps the thyroid gland producing a hormone

What happens if you don't get enough iodine?

The human thyroid will grow to abnormal size and wont produce the hormone, this is called goiter

How much iodine is enough and where can you find iodine in foods?

15 milligrams and seafood and iodized salt

What is an example of a trace element that is required by all organisms?

Iron is needed, iodine is only needed inverterabrates

Some naturally occurring elements are?

Toxic to humans and other organisms, like asrenic

How can arsenic get in water?

Arsenic occurs naturally and can makes it way into underground water sources which contaminates it and is drilled up and when drunk can cause a varitey of diseases and can be fatal, this is a promblem in south asia

What are the trace elements required by humans?

Boron, chromium, cobalt, copper, fluorine, iodine, iron, manganese, molybdnum, selenium, silicon, tin, vanadium and zinc

Some species have become adpated to?

environments that contain elements that are toxic, an example of this is serpetine communities

What is serpentine?

A jade like mineral which contains high amounts of element like nickel, cobalt and chromium

Most species of plants can't survive in serpentine conditions but some?

Have adaptions that allow them to surive

Presumably, variants of ancestral, nonserpentine speicies arose?

that could surive in serpentine soils and through natural selection a diverse range off species was produced

Reseachers are studying whether serpentine commuinites could be used to?

Take up toxic heavy metals in contaminated areas, concentrating them for safer disposal

What is this plant that is serpentine resisant?

What is this plant that is serpentine resisant?

Tiburon mariposa lily

Each element consists of atoms that are?

specific to that atom and cant be found in other atoms

What is an atom?

The smallest unit of matter that still retains properties of an element

What are atoms composed of?

Subatomic particles, one here are protons neutrons and electrons

Reseachers have discovered over a hundred different type of particles by?

using high energy coillsions to generate new particles

Protons and electrons are?

electrically charged, with one unit of charge in each

What is a charge on a proton, neutron and electron?

A proton is positively charged, electron negatively charged and a neutron is neutral

Protons and neutrons are packed tighly in the?

nucleus of an atom, with the protons giving it a positive charge

How are the electrons attracted to it?

The electrons that are rapidly moving around are attracted to the + charge of the nucleus which keeps them close

Neutrons and protons weigh about what in grams?

1.7 to the 10 to the power of negative 24

Why are grams not useful in weighing atoms?

Because they weigh so little, grams are to big

What do we use instead to weigh atoms and molecules?

Daltons named after john dalton, british scientist who helped develop atomic theory around 1800, a proton and eletron are about 1 dalton each

The dalton is the same as?

The atomic mass unit of amu

Why can we ingore the weight of electrons in calcultaing masses in atoms?

Because they weight about 1/2000 when compared to a proton or neutron

Atoms of the various elements have different number of?

Subatomic particles in the atoms

All elements of a particular element have the same bumber of?

protons in their nuclei

The number of protons is known as?

The atomic number

An atom is normally?

neutral, meaning it has the same number of protons and electrons

What number can be used to decude the number of neutrons in an atom?

The mass number

How can we find the neutron number?

Mass number take away the atomic number

What is the simplest atom?

Hydrogen which has no neutrons

Why is most of the atoms mass from the nucleus?

Because the electrons weight compared to the nucleus is tiny

In daltons how much does sodium weigh?

29.9898 daltons

What is an isotope?

A isotope of a element is an atom which has the same number of protons but a different number of neutrons which give it a greater mass

In nature an element occurs as?

a mixture of isotopes

How many isotopes does carbon have?

carbon 12, carbon 13 and carbon 14

What is the most common isotope of the element carbon?

carbon 12, which makes up 99% of the natural carbon found in nature

Isotopes of a element may have greater mass, but they behave the same in a?

Chemical reaction

Both carbon 12 and 13 are?

stable isotopes meaning that they dont give off random particles from their nuclei, this is called decay

What is a radioactive isotope?

A nucleus decays randomly, giving off particles and energy, if a proton is given off then the element converts to the new number of protons element

Radioactive isotopes have many useful applicatios in?

Biology

Cells can use radioactive atoms just the way they would use?

a non radioactive variant of the element

How are the radioactive isotopes used as diagnostic tools in medicine?

Incorperated into biologically active molecules, which are then used as tracers to track atoms during metabolism

For example how are kidney disorders diagnosed?

By injecting small doses of radioactive labeled sunstances into the blood and then analysing the tracers moleucles excreted in the urine

Radioactive tracers are also used in?

sophisticated imaging devices, like PET scanners that can moniter growth and metabolsim of cancers in the body

What from the isotopes can be damging to cells?

The cells in the body are effected by the radiation, the damage depends on the amount and type of the radiation

What is an example of one of the most serious enviromental threats from radioactive fallout?

A nuclear meltdown like three mile island

The doses of most isotopes used in medical diagnosis are?

relatively safe

What does PET stand for?

Positron-emission tomography

Researchers measure radioactive decay in fossils to?

Date them to see how old they are

Fossils provide a large body of evidence for?

evolution, documenting differences between organisms from the past and those living at present and gives us insight into the species that have dissapered over time

While the layering of fossil beds establishes that?

the deeper the fossil, the older the fossil, we cannot determine the actually age based on position alone

A parent isotope decays into a?

Daughter isotope at a fixed rate, known as r=the half life of an atom

What is halflife?

The amount of time it takes for 50 % of the parent isotope to decay

Each radioactive isotope has a half life that is not effected by?

temperature, pressure or any other enviromental vairable

Using radiometric dating scientists measure the ratio of?

different isotopes and calculate how many half lives have passed since an organisms was fossilized or a rock was formed

Half life ranges vary from?

a few seconds to a billion years

Uranium 238 has a half life of?

4.5 billion years

Uranium 238 was used to determine?

that rocks on the moon are roughly 4.5 billions years old

When two atoms approach each other during a chemical reaction, their nuclei?

don't react as they can't reach each other

Of the three subatomic particles we have looked at, what one is directly involved in chemical reactions?

electrons

An atoms electrons vary in the amount of?

energy the possess

Energy is defined as?

the capacity to cause change

Potential energy is the energy that?

matter possess because of its location or structure

For example, water in a resivour on a hill has?

potential energy because of its altitude

When the gates are opened?

the water runs downhill, the energy can be used to do work such as moving a turbine to generate electricty, becuase the energy has expended, the water has less energy it had when it was at the top of the hill

Matter has a natural tendency to move towards?

the lowest possible state of potential energy, in our example the water flowing down the hill

To restore pe of a reservoir?

work must be done to elevate the water against gravity

The electrons of an atom have potential energy due to?

their distance from the nucleus

The negatively charged electrons are attracted to?

the positively charged nucleus, so it takes more work to move a given eletron farther away from the nucleus

So the more distant an electron from the nucleus?

the higher its potenital energy

Changes in potential energy in electrons can only occur in?

steps of fixed amounts

Similarly, an electrons pe is also determined by?

its energy level

An electron can only exist?

at certain energy levels, not between them

An electrons energy level is correlated with its?

average distance from the nucleus

Electrons can be found?

in different elctron shells, each with its own average distance and energy level

An electron can move from one shell to another, but only by?

absorbing or losing an amount of energy equal to the difference in pe bewteen ist position in the old shell and that in the new shell

When an electron absorbs energy it?

moves to a shell further from the nucleus

When an electron loses energy it?

falls back to a shell closer to the nucleus, and the lost energy is usally given back to the enviroment as heat

For example, sunlight excites electrons in?

the surface of a car to a higher energy levels, when the electrons move back to their original levels, the cars surface heats up, this thermal energy can be transferred to the air or to your hand if you touch the car

The chemical behavior of an atom is determined by?

the distribution of electrons in the atoms shells

The first shell can obly hold

2 electrons

In an atom with more than 2 electrons then extra electrons must?

occupy the next shell as the first one is full

The second shell holds a max of?

8 electrons

The chemical behaviour of an atom depends mostly on the?

outermost shell of the atom

We call the outer shell and outer elctrons?

Valence shell and Valence electrons

Atoms with similiar number of valence elctrons exhibit?

similiar behaviour duirng chemical reactions

Sodium fluriode is used?

commonly in tooth paste to prevent tooth decay

An atom with a full outer shell is?

unable to react with atoms

These elements with full outer shells are said to?

be inert, chemically unreactive

In the early 1900s, the electron shells of an atom were visualized as?

concentric paths of electrons orbiting the nucleus, somewhat like planets orbiting the sun

In reality we can never know?

the true location on an electron

What can we do instead?

describe the space in which an electron spends most of its time

What is an orbital?

The three dimensional space where an electron is found 90%

Each electron shell contains?

electrons at a particular energy level, distributed among a specific number of orbitals of distinctive shapes and orientations

The first shell has only?

one spherical s orbital called 1s

The second shell has?

4 orbitals, one large spherical orbital called 2s and 3 dumbbell-shaped p orbitals called 2p orbitals

No more than?

2 electron can occupy 1 orbital

Electrons in each of the four orbitals have?

nearly the same energy, but they move in different volumes of space

The reactivity of an atom arises?

from the presence of unpaired electrons in one or more orbitals in the valence shells

What is a covalent bond?
Is the sharing of valence electrons by two atoms

Two or more atoms held together by covalent bonds consititue a?

molecule, in this case hydrogen, when 2 hydrogen molecules overlap
Hydrogens molecular formula indicates?
that the molecule consists of two atoms of hydrogen
Electron sharing can be depicted by?
an electron distribution diagram or by a lewis dot structure
What is a lewis dot structure?
in which element symbols are surrounded by dots that represent the valence electrons
We can also use a?
structural formula h-h, where the line represents a single bond, a pair of shared electrons
A space filling model comes closest to?
representing the actual shape of molecules
Oxygen has 6 electrons in the valence shell and therefore?
needs 2 more electrons to complete the valence shell
Two oxygen atoms form a molecule by?
sharing 2 pairs of valence electrons

What are the electrons in the oxygen held together by?

A double bond

Each atom that can share valence electrons has a bonding?

capacity corresponding to the number of covalent bonds that the atom can form

When the atom forms, the bonds give the atom a?

full shell of outer eletcrons

This bonding capacity is called the atom's?

valence and usally equals the number of unpaired electrons required to complete the valence shell of the atom

The molecules h2 and o2 are pure elemenets because?

they are made up of one element, where as a compound is composed of 2 or more different elements

Methane is the main component of?

natural gas with the formula CH4

How is a covalent bond formed?

when some atoms approach each other and need to fill a shell, the nucleus from each atoms attracts the electrons from the other atom and share electrons with each other to statify the atoms valence

Atoms in a molecule attract shared electrons to?

different degrees, depending on the element

What is the electronegativity of a covalent bond?

The attraction of a particular atom for the electrons in a covalent bond

The more electronegative an atom is?

the more strongly it pulls shared electrons towards its self

In a covalent bond between 2 atoms of the same element, the electrons are?

shared equally because the 2 atoms have the same electronegativity, the tug of war is at a stand off, this is known as a nonpolar covalent bond

However, when an atom is bonded to a more electronegative atom, the electrons are?

not shared evenly between the bond, this type of bond is called a polar covalent bond

Polar covalent bonds vary in their?

polarity, depending on the relative eletronegavitivty of the 2 atoms

Oxygen is one of the most?

electronegative elements, attracting shared electrons much strongly than hydrogen

In a covalent bond between oxygen and hydrogen, the electrons spend more time at?

the oxygen nucleus then at the hydrogen nucleus

Because electrons are negativily charged then?

they are pulled towards the oxugen nucleus giving the nucleus a parital negative charge and each hydrogen has a parital positive charge

In some cases, 2 atoms are so unequal in their attraction for valence electrons that the more?

electronegative atom strips an electron completely away from its partner

The 2 resultinf oppositely charged atoms or moleucles are known as?

ions

A positive ion is called a?

cation

A negative ion is called ?

anion

Because of their opposite charges, cations and anions attract?

each other, this attraction is called a ionic bond

Note that the transfer of an electron is not?

by itself, the formation of a bond: rather, it allows a bond to form because it results in 2 ions of opposite charge.

Any two ions of opposite charge can form?

an ionic bond, the ions do not need to have acquired their charge by an electron transfer with each other

Compounds formed by ionic bonds are known as?

ionic compounds or salts

Salts are often found in nature as?

crystals of various shapes and sizes.

Each salt crystal is an aggregate of?

vast number of cations and anions bonded by their electrical attraction and arranged in a 3 dimensional lattice

Unlike a covalent compound, which consits of?

molecules having a definite size and number of atoms , an ionic compound does not consist of molecules

The formula for an ionic compound, such as NaCI indicates only?

the ratio of elements in a crystal of a salt, Sodium chloride in not a molecule

Not all salts have a equal number of?

cations and anions

For example, the ionic compound magnesium chloride has 2?

chloride ions for each magnesium ion

The term ion also applies to?

entire molcules that are electrically charged

In the salt ammonium chloride, the anion is a?

single chloride ion but the cation is ammonium, a nitrogen atom covalently bonded to four hydrogen atoms. The whole ammonium ion has an electrical charge of 1+ becuase it has given up 1 electron and thus is 1 short

Enviroment affects?

the strength of ionic bonds

In a dry salt crystal, the bonds are so strong that?

it takes a hammer and chisel to break enough of them to crack they crystal in two

Most drugs are manufactured as salts because?

they are quite stable when dry but can come apart easily in water

When a hydrogen atom is covalently bonded to an?
electronegative atom, the hydrogen atom has a partial positive charge that allows it to be attracted to a different electronegative atom nearby

This attraction between a hyrdogen and an electronegative atom is called a?

hydrogen bond

In living cells, the electronegative partners are usally?

oxygen or nitrogen atoms
Even a molecule with nonpolar covalent bonds may?
have positively and negatively charged regions.

Electrons are not always evenly,

distributed at any instant, they may accumulate by chance in one part of a molecule or another
The results are ever changing?
regions of positive and negative charge that enables all atoms and molecules to stick to one another
These van der waals interactions are?
individually weak and occur only when atoms and molecules are very close together
When many such interactions occur simultaneously, however?
they can be very powerful: Van der waals interactions allow a gecko lizard to walk straight up a wall
The anatomy of a gecko's foot including?
many minuscule hair like projections from the toes and strong tendons underlying the skin - strikes a balance between maximum surface contact with the wall and necessary stiffness of the foot.
The vans der waals interactions between the foot molecules and the?
molecules of the wall's surface are so numerous that despite their individual weakness, together they can support the gecko's body weight
This discovery has inspired development of an?
artificial adhesive called Geckskin
A patch of geckskin the size of an index card can?
hold a 700 pound weight to a wall
Van der waals interactions, hydrogen bonds, ionic bonds in water and other weak bonds may form not only between molecules but also?
between parts of a large molecule, such as a protein
The cumulative effect of weak bonds is to?
reinforce the three dimensional shape of the molecule
A molecule has a characteristic size and?
precise shape, which are crucial to its function in the living cell
A molecule consisting of 2 atoms such O2, is always?
linear, but most molecules with more than 2 atoms have more complicated shapes
These shapes are determined by?
the position of the atoms orbitals
When an atom forms covalent bonds, the orbitals in its valence shell undergo?
rearrangement
For atoms with valence electrons in both s and p orbitals form?
the single s and three p orbitals form 4 new hybrid orbitals shaped like identical teardrops extending from the region of the atomic nucleus
If we connect the larger ends of teardrops with lines we form a?
tetrahedron, a pyramid with a triangle base
For water molecules, two of the hybrid orbitals in?
the oxygen's valence shell are shared with hydrogens
The result is a?
molecule shaped roughly like a V, with its two covalent bonds at an angle of 104.5 degrees
The methane molecule has the shape of?
a completed tetrahedron because all 4 hybrid orbitals of the carbon atoms are shared with the hydrogen atoms
The carbon nucleus is at the?
centre, with its four covalent bonds radiating to the hydrogen nuclei at the corner of the tetrahedron

Larger molecules containing multipule carbon atoms, including many of the molecules that make up living matter have?

more complex overall shapes

However, the tetrahedral shape of a carbon atom bonded to four other atoms is often a?

motif within such molecules

Molecular shape is crucial, it determines?

how biological molecules recognize and respond to one another with specificity

Biological molecules often bind?

temporarily to each other by forming weak chemical bonds

But only if?

their shapes are complementary

Consider the effects of opaites, such as morphine and heroin dervied from?

opium

Opiates releive?

pain and alter mood by weakly binding to specific receptor molecules on the surface of the brain

In 1975 what was discovered?

endorphines

What are endophins?

are signaling molecules made by the puiltary gland that bind to the receptors, reliving pain and producing euphoria during times of stress, such as intense excercise

Opiates have shapes similar to?

endorphines and mimic them by binding to endorphin receptors in the brain

This is why opiates and endorphins have?

similiar effects

The making of chemical bonds, leading to?

changes in composition of matter, called chemical bonds

The starting materails are called?

reactants to the products

Matter is?

consevered in a chemical reaction

Reactions can't

create or destroy electrons, but can rearange the electrons among the atoms

What is the chemical reaction for photosynthesis?

6C02 + 6H20 - C6H12O6 + 6O2

The raw materials of photosynthesis are?

carbon dioxide, which is taken from the air and water which is abosbed from the soil

within plant cells sunlight powers the?

conversion of these ingredients into glucose and oxygen molecules

All chemical reactions are?

reversible, with the prodcuts of the forward reaction becoming the reactants for the reverse reaction

One of the factors effecting rate of reaction is?

the concentration of reactants. The greater the concentration of reactant molecules, the more collisions with one another, so a higher chance of reacting, so more product is formed. Can be reversed for products

Eventually, the forward and revrse reactions occur at?

the same rate, and the relative concentrations of products and reactants stop changing

The point at which the reactions offset one another excatly is called the?

chemical equilibrium

This is a dynamic equilibrium, reactions are?

still going on, but with no net effect on the concentrations of reactants and products

Equilibrium does not mean?

that the reactants and products are equal in concentration, but only that their concentrations have stabilized at a particular ratio

In some chemical reactions, the equilibrium point may lie so?

far to the right that these reactions go essentially to completion, where almost of all the reactants have been converted to products

What plant is this?

What plant is this?

Elodea, a fresh water plant.