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214 Cards in this Set
- Front
- Back
Wood ants live in coloines of up to? |
thousands of ants in a single colony |
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Colonies of wood ants have a mechanism to deal with threats, what is it? |
To fire folic acid from their abodmens which rains down on their attackers |
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Some species of ants don't use it as a firing mechanism, what do they use it for instead? |
Spray on themselves as a defense against microbes |
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Where did folic acid gets it name from? |
The latin word for ant, formica |
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Scientists have long known chemicals play a role in? |
Serveal different aspects of ant behaviour insect communication, defence and attraction of mates |
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Organisms are composed of? |
Matter which is anything that takes up space and has mass |
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What is matter made up of? |
Elements |
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What is an element? |
An element is a substance that cannot be chemically broken down into a simpler form |
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Chemists recognize how many natural elements? |
92 |
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Each element has a symbol derived from? |
Usally from the first letter or two of its name, some symbols are derived from latin or german, natrium for sodium for example |
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What is a compound? |
A compound is a substance consisting of 2 of more different elements in a fixed ratio |
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Table salt for example is? |
Sodium Chloride |
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What is pure sodium and pure chlroine? |
Pure sodium is a metal and pure chlorine is a toxic gas |
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A compound has characteristics different from? |
Those of the original elements that made it up |
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Define mass |
Mass is the amount of matter in something where as the weight of an object is how strong gravity pulls on matter in the object |
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Out of the 92 elements as a % barrier, what is the boundary? |
Out of the 92 elements, between 20 and 25 per cent are essential elements |
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There is some variation in elements? |
Between organims, for example some organisms require more than another, like a human needs 25 elements and plants need 17 |
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What 4 elements make up 96.3% of living matter? |
Oxygen 65%, Carbon 18.5%, Hydrogen, 9.5% and Nitrogen 3.3% |
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Trace elements are reuqired in? |
Small doses as they are not required in large doses, like iodine which keeps the thyroid gland producing a hormone |
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What happens if you don't get enough iodine? |
The human thyroid will grow to abnormal size and wont produce the hormone, this is called goiter |
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How much iodine is enough and where can you find iodine in foods? |
15 milligrams and seafood and iodized salt |
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What is an example of a trace element that is required by all organisms? |
Iron is needed, iodine is only needed inverterabrates |
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Some naturally occurring elements are? |
Toxic to humans and other organisms, like asrenic |
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How can arsenic get in water? |
Arsenic occurs naturally and can makes it way into underground water sources which contaminates it and is drilled up and when drunk can cause a varitey of diseases and can be fatal, this is a promblem in south asia |
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What are the trace elements required by humans? |
Boron, chromium, cobalt, copper, fluorine, iodine, iron, manganese, molybdnum, selenium, silicon, tin, vanadium and zinc |
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Some species have become adpated to? |
environments that contain elements that are toxic, an example of this is serpetine communities |
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What is serpentine? |
A jade like mineral which contains high amounts of element like nickel, cobalt and chromium |
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Most species of plants can't survive in serpentine conditions but some? |
Have adaptions that allow them to surive |
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Presumably, variants of ancestral, nonserpentine speicies arose? |
that could surive in serpentine soils and through natural selection a diverse range off species was produced |
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Reseachers are studying whether serpentine commuinites could be used to? |
Take up toxic heavy metals in contaminated areas, concentrating them for safer disposal |
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What is this plant that is serpentine resisant? |
Tiburon mariposa lily |
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Each element consists of atoms that are? |
specific to that atom and cant be found in other atoms |
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What is an atom? |
The smallest unit of matter that still retains properties of an element |
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What are atoms composed of? |
Subatomic particles, one here are protons neutrons and electrons |
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Reseachers have discovered over a hundred different type of particles by? |
using high energy coillsions to generate new particles |
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Protons and electrons are? |
electrically charged, with one unit of charge in each |
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What is a charge on a proton, neutron and electron? |
A proton is positively charged, electron negatively charged and a neutron is neutral |
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Protons and neutrons are packed tighly in the? |
nucleus of an atom, with the protons giving it a positive charge |
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How are the electrons attracted to it? |
The electrons that are rapidly moving around are attracted to the + charge of the nucleus which keeps them close |
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Neutrons and protons weigh about what in grams? |
1.7 to the 10 to the power of negative 24 |
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Why are grams not useful in weighing atoms? |
Because they weigh so little, grams are to big |
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What do we use instead to weigh atoms and molecules? |
Daltons named after john dalton, british scientist who helped develop atomic theory around 1800, a proton and eletron are about 1 dalton each |
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The dalton is the same as? |
The atomic mass unit of amu |
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Why can we ingore the weight of electrons in calcultaing masses in atoms? |
Because they weight about 1/2000 when compared to a proton or neutron |
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Atoms of the various elements have different number of? |
Subatomic particles in the atoms |
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All elements of a particular element have the same bumber of? |
protons in their nuclei |
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The number of protons is known as? |
The atomic number |
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An atom is normally? |
neutral, meaning it has the same number of protons and electrons |
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What number can be used to decude the number of neutrons in an atom? |
The mass number |
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How can we find the neutron number? |
Mass number take away the atomic number |
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What is the simplest atom? |
Hydrogen which has no neutrons |
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Why is most of the atoms mass from the nucleus? |
Because the electrons weight compared to the nucleus is tiny |
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In daltons how much does sodium weigh? |
29.9898 daltons |
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What is an isotope? |
A isotope of a element is an atom which has the same number of protons but a different number of neutrons which give it a greater mass |
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In nature an element occurs as? |
a mixture of isotopes |
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How many isotopes does carbon have? |
carbon 12, carbon 13 and carbon 14 |
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What is the most common isotope of the element carbon? |
carbon 12, which makes up 99% of the natural carbon found in nature |
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Isotopes of a element may have greater mass, but they behave the same in a? |
Chemical reaction |
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Both carbon 12 and 13 are? |
stable isotopes meaning that they dont give off random particles from their nuclei, this is called decay |
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What is a radioactive isotope? |
A nucleus decays randomly, giving off particles and energy, if a proton is given off then the element converts to the new number of protons element |
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Radioactive isotopes have many useful applicatios in? |
Biology |
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Cells can use radioactive atoms just the way they would use? |
a non radioactive variant of the element |
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How are the radioactive isotopes used as diagnostic tools in medicine? |
Incorperated into biologically active molecules, which are then used as tracers to track atoms during metabolism |
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For example how are kidney disorders diagnosed? |
By injecting small doses of radioactive labeled sunstances into the blood and then analysing the tracers moleucles excreted in the urine |
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Radioactive tracers are also used in? |
sophisticated imaging devices, like PET scanners that can moniter growth and metabolsim of cancers in the body |
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What from the isotopes can be damging to cells? |
The cells in the body are effected by the radiation, the damage depends on the amount and type of the radiation |
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What is an example of one of the most serious enviromental threats from radioactive fallout? |
A nuclear meltdown like three mile island |
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The doses of most isotopes used in medical diagnosis are? |
relatively safe |
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What does PET stand for? |
Positron-emission tomography |
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Researchers measure radioactive decay in fossils to? |
Date them to see how old they are |
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Fossils provide a large body of evidence for? |
evolution, documenting differences between organisms from the past and those living at present and gives us insight into the species that have dissapered over time |
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While the layering of fossil beds establishes that? |
the deeper the fossil, the older the fossil, we cannot determine the actually age based on position alone |
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A parent isotope decays into a? |
Daughter isotope at a fixed rate, known as r=the half life of an atom |
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What is halflife? |
The amount of time it takes for 50 % of the parent isotope to decay |
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Each radioactive isotope has a half life that is not effected by? |
temperature, pressure or any other enviromental vairable |
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Using radiometric dating scientists measure the ratio of? |
different isotopes and calculate how many half lives have passed since an organisms was fossilized or a rock was formed |
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Half life ranges vary from? |
a few seconds to a billion years |
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Uranium 238 has a half life of? |
4.5 billion years |
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Uranium 238 was used to determine? |
that rocks on the moon are roughly 4.5 billions years old |
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When two atoms approach each other during a chemical reaction, their nuclei? |
don't react as they can't reach each other |
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Of the three subatomic particles we have looked at, what one is directly involved in chemical reactions? |
electrons |
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An atoms electrons vary in the amount of? |
energy the possess |
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Energy is defined as? |
the capacity to cause change |
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Potential energy is the energy that? |
matter possess because of its location or structure |
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For example, water in a resivour on a hill has? |
potential energy because of its altitude |
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When the gates are opened? |
the water runs downhill, the energy can be used to do work such as moving a turbine to generate electricty, becuase the energy has expended, the water has less energy it had when it was at the top of the hill |
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Matter has a natural tendency to move towards? |
the lowest possible state of potential energy, in our example the water flowing down the hill |
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To restore pe of a reservoir? |
work must be done to elevate the water against gravity |
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The electrons of an atom have potential energy due to? |
their distance from the nucleus |
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The negatively charged electrons are attracted to? |
the positively charged nucleus, so it takes more work to move a given eletron farther away from the nucleus |
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So the more distant an electron from the nucleus? |
the higher its potenital energy |
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Changes in potential energy in electrons can only occur in? |
steps of fixed amounts |
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Similarly, an electrons pe is also determined by? |
its energy level |
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An electron can only exist? |
at certain energy levels, not between them |
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An electrons energy level is correlated with its? |
average distance from the nucleus |
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Electrons can be found? |
in different elctron shells, each with its own average distance and energy level |
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An electron can move from one shell to another, but only by? |
absorbing or losing an amount of energy equal to the difference in pe bewteen ist position in the old shell and that in the new shell |
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When an electron absorbs energy it? |
moves to a shell further from the nucleus |
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When an electron loses energy it? |
falls back to a shell closer to the nucleus, and the lost energy is usally given back to the enviroment as heat |
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For example, sunlight excites electrons in? |
the surface of a car to a higher energy levels, when the electrons move back to their original levels, the cars surface heats up, this thermal energy can be transferred to the air or to your hand if you touch the car |
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The chemical behavior of an atom is determined by? |
the distribution of electrons in the atoms shells |
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The first shell can obly hold |
2 electrons |
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In an atom with more than 2 electrons then extra electrons must? |
occupy the next shell as the first one is full |
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The second shell holds a max of? |
8 electrons |
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The chemical behaviour of an atom depends mostly on the? |
outermost shell of the atom |
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We call the outer shell and outer elctrons? |
Valence shell and Valence electrons |
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Atoms with similiar number of valence elctrons exhibit? |
similiar behaviour duirng chemical reactions |
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Sodium fluriode is used? |
commonly in tooth paste to prevent tooth decay |
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An atom with a full outer shell is? |
unable to react with atoms |
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These elements with full outer shells are said to? |
be inert, chemically unreactive |
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In the early 1900s, the electron shells of an atom were visualized as? |
concentric paths of electrons orbiting the nucleus, somewhat like planets orbiting the sun |
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In reality we can never know? |
the true location on an electron |
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What can we do instead? |
describe the space in which an electron spends most of its time |
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What is an orbital? |
The three dimensional space where an electron is found 90% |
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Each electron shell contains? |
electrons at a particular energy level, distributed among a specific number of orbitals of distinctive shapes and orientations |
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The first shell has only? |
one spherical s orbital called 1s |
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The second shell has? |
4 orbitals, one large spherical orbital called 2s and 3 dumbbell-shaped p orbitals called 2p orbitals |
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No more than? |
2 electron can occupy 1 orbital |
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Electrons in each of the four orbitals have? |
nearly the same energy, but they move in different volumes of space |
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The reactivity of an atom arises? |
from the presence of unpaired electrons in one or more orbitals in the valence shells |
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What is a covalent bond?
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Is the sharing of valence electrons by two atoms
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Two or more atoms held together by covalent bonds consititue a? |
molecule, in this case hydrogen, when 2 hydrogen molecules overlap
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Hydrogens molecular formula indicates?
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that the molecule consists of two atoms of hydrogen
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Electron sharing can be depicted by?
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an electron distribution diagram or by a lewis dot structure
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What is a lewis dot structure?
|
in which element symbols are surrounded by dots that represent the valence electrons
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We can also use a?
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structural formula h-h, where the line represents a single bond, a pair of shared electrons
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A space filling model comes closest to?
|
representing the actual shape of molecules
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Oxygen has 6 electrons in the valence shell and therefore?
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needs 2 more electrons to complete the valence shell
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Two oxygen atoms form a molecule by?
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sharing 2 pairs of valence electrons
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What are the electrons in the oxygen held together by? |
A double bond |
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Each atom that can share valence electrons has a bonding? |
capacity corresponding to the number of covalent bonds that the atom can form |
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When the atom forms, the bonds give the atom a? |
full shell of outer eletcrons |
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This bonding capacity is called the atom's? |
valence and usally equals the number of unpaired electrons required to complete the valence shell of the atom |
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The molecules h2 and o2 are pure elemenets because? |
they are made up of one element, where as a compound is composed of 2 or more different elements |
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Methane is the main component of? |
natural gas with the formula CH4 |
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How is a covalent bond formed? |
when some atoms approach each other and need to fill a shell, the nucleus from each atoms attracts the electrons from the other atom and share electrons with each other to statify the atoms valence |
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Atoms in a molecule attract shared electrons to? |
different degrees, depending on the element |
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What is the electronegativity of a covalent bond? |
The attraction of a particular atom for the electrons in a covalent bond |
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The more electronegative an atom is? |
the more strongly it pulls shared electrons towards its self |
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In a covalent bond between 2 atoms of the same element, the electrons are? |
shared equally because the 2 atoms have the same electronegativity, the tug of war is at a stand off, this is known as a nonpolar covalent bond |
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However, when an atom is bonded to a more electronegative atom, the electrons are? |
not shared evenly between the bond, this type of bond is called a polar covalent bond |
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Polar covalent bonds vary in their? |
polarity, depending on the relative eletronegavitivty of the 2 atoms |
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Oxygen is one of the most? |
electronegative elements, attracting shared electrons much strongly than hydrogen |
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In a covalent bond between oxygen and hydrogen, the electrons spend more time at? |
the oxygen nucleus then at the hydrogen nucleus |
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Because electrons are negativily charged then? |
they are pulled towards the oxugen nucleus giving the nucleus a parital negative charge and each hydrogen has a parital positive charge |
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In some cases, 2 atoms are so unequal in their attraction for valence electrons that the more? |
electronegative atom strips an electron completely away from its partner |
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The 2 resultinf oppositely charged atoms or moleucles are known as? |
ions |
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A positive ion is called a? |
cation |
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A negative ion is called ? |
anion |
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Because of their opposite charges, cations and anions attract? |
each other, this attraction is called a ionic bond |
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Note that the transfer of an electron is not? |
by itself, the formation of a bond: rather, it allows a bond to form because it results in 2 ions of opposite charge. |
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Any two ions of opposite charge can form? |
an ionic bond, the ions do not need to have acquired their charge by an electron transfer with each other |
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Compounds formed by ionic bonds are known as? |
ionic compounds or salts |
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Salts are often found in nature as? |
crystals of various shapes and sizes. |
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Each salt crystal is an aggregate of? |
vast number of cations and anions bonded by their electrical attraction and arranged in a 3 dimensional lattice |
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Unlike a covalent compound, which consits of? |
molecules having a definite size and number of atoms , an ionic compound does not consist of molecules |
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The formula for an ionic compound, such as NaCI indicates only? |
the ratio of elements in a crystal of a salt, Sodium chloride in not a molecule |
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Not all salts have a equal number of? |
cations and anions |
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For example, the ionic compound magnesium chloride has 2? |
chloride ions for each magnesium ion |
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The term ion also applies to? |
entire molcules that are electrically charged |
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In the salt ammonium chloride, the anion is a? |
single chloride ion but the cation is ammonium, a nitrogen atom covalently bonded to four hydrogen atoms. The whole ammonium ion has an electrical charge of 1+ becuase it has given up 1 electron and thus is 1 short |
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Enviroment affects? |
the strength of ionic bonds |
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In a dry salt crystal, the bonds are so strong that? |
it takes a hammer and chisel to break enough of them to crack they crystal in two |
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Most drugs are manufactured as salts because? |
they are quite stable when dry but can come apart easily in water |
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When a hydrogen atom is covalently bonded to an?
|
electronegative atom, the hydrogen atom has a partial positive charge that allows it to be attracted to a different electronegative atom nearby
|
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This attraction between a hyrdogen and an electronegative atom is called a? |
hydrogen bond |
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In living cells, the electronegative partners are usally? |
oxygen or nitrogen atoms
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Even a molecule with nonpolar covalent bonds may?
|
have positively and negatively charged regions.
|
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Electrons are not always evenly, |
distributed at any instant, they may accumulate by chance in one part of a molecule or another
|
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The results are ever changing?
|
regions of positive and negative charge that enables all atoms and molecules to stick to one another
|
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These van der waals interactions are?
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individually weak and occur only when atoms and molecules are very close together
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When many such interactions occur simultaneously, however?
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they can be very powerful: Van der waals interactions allow a gecko lizard to walk straight up a wall
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The anatomy of a gecko's foot including?
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many minuscule hair like projections from the toes and strong tendons underlying the skin - strikes a balance between maximum surface contact with the wall and necessary stiffness of the foot.
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The vans der waals interactions between the foot molecules and the?
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molecules of the wall's surface are so numerous that despite their individual weakness, together they can support the gecko's body weight
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This discovery has inspired development of an?
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artificial adhesive called Geckskin
|
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A patch of geckskin the size of an index card can?
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hold a 700 pound weight to a wall
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Van der waals interactions, hydrogen bonds, ionic bonds in water and other weak bonds may form not only between molecules but also?
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between parts of a large molecule, such as a protein
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The cumulative effect of weak bonds is to?
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reinforce the three dimensional shape of the molecule
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A molecule has a characteristic size and?
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precise shape, which are crucial to its function in the living cell
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A molecule consisting of 2 atoms such O2, is always?
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linear, but most molecules with more than 2 atoms have more complicated shapes
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These shapes are determined by?
|
the position of the atoms orbitals
|
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When an atom forms covalent bonds, the orbitals in its valence shell undergo?
|
rearrangement
|
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For atoms with valence electrons in both s and p orbitals form?
|
the single s and three p orbitals form 4 new hybrid orbitals shaped like identical teardrops extending from the region of the atomic nucleus
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If we connect the larger ends of teardrops with lines we form a?
|
tetrahedron, a pyramid with a triangle base
|
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For water molecules, two of the hybrid orbitals in?
|
the oxygen's valence shell are shared with hydrogens
|
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The result is a?
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molecule shaped roughly like a V, with its two covalent bonds at an angle of 104.5 degrees
|
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The methane molecule has the shape of?
|
a completed tetrahedron because all 4 hybrid orbitals of the carbon atoms are shared with the hydrogen atoms
|
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The carbon nucleus is at the?
|
centre, with its four covalent bonds radiating to the hydrogen nuclei at the corner of the tetrahedron
|
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Larger molecules containing multipule carbon atoms, including many of the molecules that make up living matter have? |
more complex overall shapes
|
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However, the tetrahedral shape of a carbon atom bonded to four other atoms is often a? |
motif within such molecules |
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Molecular shape is crucial, it determines? |
how biological molecules recognize and respond to one another with specificity |
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Biological molecules often bind? |
temporarily to each other by forming weak chemical bonds |
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But only if? |
their shapes are complementary |
|
Consider the effects of opaites, such as morphine and heroin dervied from? |
opium |
|
Opiates releive? |
pain and alter mood by weakly binding to specific receptor molecules on the surface of the brain |
|
In 1975 what was discovered? |
endorphines |
|
What are endophins? |
are signaling molecules made by the puiltary gland that bind to the receptors, reliving pain and producing euphoria during times of stress, such as intense excercise |
|
Opiates have shapes similar to? |
endorphines and mimic them by binding to endorphin receptors in the brain |
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This is why opiates and endorphins have? |
similiar effects |
|
The making of chemical bonds, leading to? |
changes in composition of matter, called chemical bonds |
|
The starting materails are called? |
reactants to the products |
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Matter is? |
consevered in a chemical reaction |
|
Reactions can't |
create or destroy electrons, but can rearange the electrons among the atoms |
|
What is the chemical reaction for photosynthesis? |
6C02 + 6H20 - C6H12O6 + 6O2 |
|
The raw materials of photosynthesis are? |
carbon dioxide, which is taken from the air and water which is abosbed from the soil |
|
within plant cells sunlight powers the? |
conversion of these ingredients into glucose and oxygen molecules |
|
All chemical reactions are? |
reversible, with the prodcuts of the forward reaction becoming the reactants for the reverse reaction |
|
One of the factors effecting rate of reaction is? |
the concentration of reactants. The greater the concentration of reactant molecules, the more collisions with one another, so a higher chance of reacting, so more product is formed. Can be reversed for products |
|
Eventually, the forward and revrse reactions occur at? |
the same rate, and the relative concentrations of products and reactants stop changing |
|
The point at which the reactions offset one another excatly is called the? |
chemical equilibrium |
|
This is a dynamic equilibrium, reactions are? |
still going on, but with no net effect on the concentrations of reactants and products |
|
Equilibrium does not mean? |
that the reactants and products are equal in concentration, but only that their concentrations have stabilized at a particular ratio |
|
In some chemical reactions, the equilibrium point may lie so? |
far to the right that these reactions go essentially to completion, where almost of all the reactants have been converted to products |
|
What plant is this? |
Elodea, a fresh water plant. |