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33 Cards in this Set

  • Front
  • Back
Atomic Number (Z)
Number of protons in the nucleus
Atomic Mass (A)
Sum of masses of protons and neutrons
Isotopes
Same elements with different atomic masses (different number of neutrons)
Atomic Weight
Weighted average of the atomic masses of the atom's naturally occurring isotopes
Atomic Mass Unit (AMU)
Used to compute atomic weight, where one of these is 1/12 of the atomic mass of the most common isotope of carbon (Carbon12)
Quantum Mechanics
Principles of laws that govern systems of atomic and subatomic entities
Bohr Atomic Model
Electrons are assumed to revolve around the atomic nucleus in discrete orbitals
Mole
6.022E23 of anything
1 g/mol
1 amu/atom(or molecule)
Wave-Mechanical Model
Electron is considered to exhibit both wavelike and particle-like characteristics; electron is no longer treated as a particle moving in discrete orbital - position is considered to be probability of an electron's position
Quantum Numbers
Four parameters characterizing electrons: size, shape, orientation electron subshells
Shells
Specified by principal quantum number n
Designated by K, L, M, N, O
Corresponds to n = 1, 2, 3, 4, 5
Subshell
Signified by second quantum number: s, p, d, f
Spin movement
Up or down, possible values of +1/2 or -1/2
Electron States
Values of energy permitted for electrons
Pauli Exclusion Principle
Each electron state can hold no more than two electrons, which must have opposite spins
Ground State
All electrons occupy the lowest possible energies in accord with the foregoing restrictions
Electron configuration
Structure of an atom represents the manner in which states are occupied
Valence Electrons
Electrons that occupy the outermost shell
Stable Electron Configurations
Outermost shell is filled
Periodic table
Elements classified according to electron configuration
Electropositive
Elements capable of giving up valence electrons to be positively charged ions (typically metals)
Electronegative
Right-hand side of periodic table; readily accept electrons to form negatively charged ions
F(N)
Net force between two atoms: F(A)+F(R) => attractive and repulsive components
Equilibrium in force
F(A)+F(R)=0
Bonding Energy
E(0) corresponds to the energy at the minimum point of the net energy curve
Primary/chemical bonds
How atoms interact
Ionic Bonding
Transfer of electrons
Coulombic
Attractive bonding forces (word for)
Attractive Energy
E(A) in E(A)=-A/r
Covalent Bonding
Atoms each contribute at least one electron to the bond
Metallic Bonding
Valence electrons are not bound and freely drift throughout the entire metal
Secondary Bond
Van der Waals
Physical Bonds
Bonding that arises from dipoles (when there is some separation of positive and negative portions of an atom or molecule)