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33 Cards in this Set
- Front
- Back
Atomic Number (Z)
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Number of protons in the nucleus
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Atomic Mass (A)
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Sum of masses of protons and neutrons
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Isotopes
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Same elements with different atomic masses (different number of neutrons)
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Atomic Weight
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Weighted average of the atomic masses of the atom's naturally occurring isotopes
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Atomic Mass Unit (AMU)
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Used to compute atomic weight, where one of these is 1/12 of the atomic mass of the most common isotope of carbon (Carbon12)
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Quantum Mechanics
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Principles of laws that govern systems of atomic and subatomic entities
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Bohr Atomic Model
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Electrons are assumed to revolve around the atomic nucleus in discrete orbitals
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Mole
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6.022E23 of anything
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1 g/mol
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1 amu/atom(or molecule)
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Wave-Mechanical Model
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Electron is considered to exhibit both wavelike and particle-like characteristics; electron is no longer treated as a particle moving in discrete orbital - position is considered to be probability of an electron's position
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Quantum Numbers
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Four parameters characterizing electrons: size, shape, orientation electron subshells
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Shells
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Specified by principal quantum number n
Designated by K, L, M, N, O Corresponds to n = 1, 2, 3, 4, 5 |
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Subshell
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Signified by second quantum number: s, p, d, f
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Spin movement
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Up or down, possible values of +1/2 or -1/2
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Electron States
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Values of energy permitted for electrons
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Pauli Exclusion Principle
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Each electron state can hold no more than two electrons, which must have opposite spins
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Ground State
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All electrons occupy the lowest possible energies in accord with the foregoing restrictions
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Electron configuration
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Structure of an atom represents the manner in which states are occupied
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Valence Electrons
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Electrons that occupy the outermost shell
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Stable Electron Configurations
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Outermost shell is filled
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Periodic table
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Elements classified according to electron configuration
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Electropositive
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Elements capable of giving up valence electrons to be positively charged ions (typically metals)
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Electronegative
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Right-hand side of periodic table; readily accept electrons to form negatively charged ions
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F(N)
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Net force between two atoms: F(A)+F(R) => attractive and repulsive components
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Equilibrium in force
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F(A)+F(R)=0
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Bonding Energy
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E(0) corresponds to the energy at the minimum point of the net energy curve
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Primary/chemical bonds
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How atoms interact
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Ionic Bonding
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Transfer of electrons
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Coulombic
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Attractive bonding forces (word for)
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Attractive Energy
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E(A) in E(A)=-A/r
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Covalent Bonding
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Atoms each contribute at least one electron to the bond
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Metallic Bonding
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Valence electrons are not bound and freely drift throughout the entire metal
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Secondary Bond
Van der Waals Physical Bonds |
Bonding that arises from dipoles (when there is some separation of positive and negative portions of an atom or molecule)
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