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24 Cards in this Set

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What is crude oil and how is it formed?

Crude oil is a fossil fuel. It was formed from living things that lived in the sea millions of years ago. these became buried deep in the seabed , after they died. Chemical reactions happened that eventually turned them into crude oil. It is non renewable, they are finite resources.

Separating crude oil

1)The different compounds in crude oil are seperated by fractional distillation.


2)The crude oil is heated until most of it has turned into gas


3)The gases enter a fractionating column, apart from the liquid bitumen which drains out at the bottom


4)In the column there is a temperature gradient, hot at the bottom and cold at the top.


5)Longer hydrocarbons have higher boiling points. they turn into liquids and drain out early on.


6)The shorter hydrocarbons have lower boiling points they turn into liquid and run out much later on, where it is cooler.


7)You end up with crude oil separated out into separate fractions. Each fraction contains a mixture of hydrocarbons with similar boiling points.



Covalent bonds

The atoms in hydrocarbon molecules are joined together with covalent bonds.

Intermolecular forces

The covalent bonds holding the atoms in hydrocarbon atoms are much stronger than intermolecular forces that attract hydrocarbon molecules together the se forces are broken when crude oil is boiled, not the covalent bonds. this causes the hydrocarbon molecules to separate from each other when they are turned into a gas.

Properties of hydrocarbons as the hydrocarbon chains get longer

The boiling point increases


It gets less flammable


It gets more viscous (does not flow as easily)


It gets less volatile (doest evaporate as easily)


Hydrocarbons with smallest molecules are gases and those with largest molecules are solids.



why do bigger hydrocarbon molecules have a high boiling point?

the intermolecular forces are much stronger, so more energy is needed to overcome the attraction.

Other problems with crude oil, environmental?

Oil tanker crashes can lead to huge amounts of crude oil being released into the sea, the oil floats on water and the action waves spreads it out into the big oil slicks.


Oil then covers the sea birds feathers, and stops them from being waterproof, they will not be able to fly plus they will die from the cold water.


detergent are often used to clean oil slicks, they break the oil into tiny droplets, which makes it easier to dispose of. however it can still damage wildlife, as they can be toxic.`

Political issues with crude oil?

As stocks of ol get used up, the price of oil will increase, so plastics and fuels will get more expensive. Countries with big stocks can just start to keep it, than selling it.


The countries with more oil have more power, can lead onto war.


It will be harder for countries with less oil to get hold of it, so we have to supply from politically unstable countries and we can be cut of at any time.

What is the point of cracking?

Cracking is a chemical process converts large hydrocarbon molecules into smaller more useful hydrocarbon molecules. Turns long alkane molecules into smaller alkane and alkene molecules. thermal decompositon.

what does cracking involve?

It needs high temp and a catalyst, it involves heating the oil fractions to a high temperature and then passing it over a catalyst.


1)vaporised hydrocarbons are passed along the powdered catalyst at about 400-700 degrees.


2)Aluminium oxide is the catalyst, the long chain hydrocarbon molecules split or crack on the surface of the bits of catalyst.

What is a fuel?

A fuel is a substance that reacts with oxygen to release useful energy. this is mostly heat energy.

Complete combustion

If there is plentiful supply of oxygen complete combustion happens. the products are not poisonous:


the carbon reacts with oxygen: carbon dioxide


the hydrogen reacts with oxygen produces water.


hydrocarbon + oxygen → carbon dioxide + water (+energy).


Many gas heaters release these waste products into the room which is okay, as long as the heater is working properly and the room is well ventilated. Complete combustion releases a lot of energy. clean blue flame.


CH4 + 2O2 → CO2 + 2H2O (Methane)

Experiment to check for complete combustion?

The water pump draws up gasses from the burning candle through the water collects in the U tube, you can check its water by checking its boiling point. also the lime water will go milky - carbon dioxide. the apparatus will turn hot, energy.

The water pump draws up gasses from the burning candle through the water collects in the U tube, you can check its water by checking its boiling point. also the lime water will go milky - carbon dioxide. the apparatus will turn hot, energy.

when does incomplete combustion happen?

When there is a shhortage of air, therefore oxygen.This sort of combustion gives off carbon monoxideand carbon as waste products, yellow flame. the carbon monoxide is colourless, odourless and poisonous it is very dangerous, no one notices it. this is why gas appliances have to be serviced regularly, checked to make sure they are getting enough oxygen. Helps appliances release more energy and less soot produced from carbon (sooty marks).


hydrocarbon + oxygen → carbon monoxide + carbon + water




C2H6 + 2O2 → CO + C + 3H2O

Factors to when choosing the right fuel?

Energy value, the amount of energy available.


availability of the fuel


storage is the fuel flammable


toxicity harmful fumes?


Ease of use , can you move it easily or not?


pollution levels.

The Earths atmosphere?

mixture of gases surrounding the planet. The Earths gravity stops these gases escaping into space. the lower part of the atmosphere is what we breathe.

Phase 1 of how the atmosphere was formed?



Volcanoes gave out steam and carbon dioxide. The Earth atmosphere was originally molten for many years and any sort of atmosphere formed was burned away. eventually it coloed and a thin crust formed, but volcanoes get erupting releasing gases from inside the earth. This released carbon dioxide, steam and ammonia. when things settled down the early atmosphere was carbon dioxide and water vapour (water vapour condensed to form oceans)

Phase 2 Green plants evolved and produced oxygen

a lot of the early carbon dioxide dissolved in the oceans, green plants evolved over most of the Earth, as they photosynthesised they removed carbon dioxide and produced oxygen. Oxygen levels increased and carbon dioxide got locked up in fossil fuels and sedimentary rocks. Nitrogen was put into the atmosphere in two ways , ammonia reacted with oxygen, and by denitrfying bacteria. Nitrogen isn't very reactive, its levels increased but didn't get broken down.

Phase 3 - ozone layer was formed which allowed the evolution of complex animals

The build up of oxygen killed of early organisms that couldn't tolerate it. But it did allow the evolution of more complex organisms that made use of oxygen. the oxygen also created the ozone layer which blocked UV rays allowing organisms to develop.

Percentage of gases in atmosphere?

nitrogen 78%


oxygen 21%


Carbon dioxde 0.04%

Describe the carbon cycle?

Carbon is continuously recycled, carbon is key to the greenhouse effect, it exists in the atmosphere are carbon dioxide gas, and it is also present in many other greenhouse gases like methane. Carbon on Earth moves in one great cycle.

What processes add carbon to the atmosphere?

Respiration, combustion and decay of dead plants and animals, they also remove oxygen.

What processes removes carbon from the atmosphere?

Photosynthesis adds oxygen into the atmosphere and removes carbon, these processes balance out.

why dont these processes balance out though?

humans have affected the natural carbon cycle, which has affected the balance of gases in the atmosphere.