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23 Cards in this Set

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Organic Chemistry

the study of carbon compounds (organic compounds)

Hydrocarbons

organic molecules consisting of only C and H

List the four ways that carbon skeletons can vary.

1. Length


2. Branching


3. Bond types/location


4. Rings

Isomer

one of several compounds with the same molecular formula but different structures and therefore different properties

List the three types of isomers.

Structural Isomers

isomers that differ in covalent partners

isomers that differ in covalent partners

Cis-Trans Isomers (Geometric Isomers)

isomers that differ in arrangement about an inflexible double bond


cis - X groups on same side
trans - X groups of different sides

isomers that differ in arrangement about an inflexible double bond




cis - X groups on same side


trans - X groups of different sides

Enantiomers

isomers that differ in spatial arrangement around asymmetric C that appear as mirror images to each other

isomers that differ in spatial arrangement around asymmetric C that appear as mirror images to each other

Functional Groups

a specific confirguration of atoms commonly attached to the carbon skeletons of organic molecules and involved in chemical reactions

Name 7 functional groups.

1. Hydroxyl group (-OH)


2. Carbonyl group (C=O)


3. Carboxyl group (-COOH)


4. Amino group (-NH2)


5. Sulfhydryl group (-SH)


6. Phosphate group (-OPO3 (2-))


7. Methyl group (-CH3)

Hydroxyl group

-OH


Compound Name: Alcohol




polar; forms H bonds with water to dissolve compounds like sugar

Carbonyl group

C=O


Compound Name: Ketone (if within skeleton) or Aldehyde (if at end of skeleton)

Carboxyl group

-COOH


Compound Name: carboxylic (organic) acid




acts as an acid due to high polarity of O-H bond

Amino group

-NH2


Compound Name: Amine




acts as a base

Sulfhydryl group

-SH


Compound name: Thiol




two molecules with -SH groups can react and form a "cross-link" to stabilize protein structures

Phosphate group

-OPO3 (-2)


Compound name: Organic phosphate




contributes a negative charge to molecule; allows molecule to react with water and release energy

Methyl group

-CH3


Compound name: Methylated compound




affects the expression of genes when on DNA or on proteins bound to DNA; affects shape/function of sex hormones

Adenosine Triphosphate

ATP




an adenine-containing nucleoside triphosphate that releases free energy when phosphate bonds are hydrolyzed; used to drive endergonic reactions in cells

ATP Reaction

(P)(P)(P)[A] +H2O -> (P1) + (P)(P)[A] + Energy




ATP and water react to form an inorganic phosphate (P1), ADP, and energy

Both _______ and _______ groups are always found in amino acids.

Both -COOH (carboxyl) and -NH2 (amine) groups are always found in amino acids.

The chemical group that is involved in regulating DNA is the ________ group.

The chemical group that is involved in regulating DNA is the methyl (-CH3) group.

The chemical group that helps stabilize protein structure is the __________.

The chemical group that helps stabilize protein structure is the sulfhydryl group (-SH).

All functional groups are (hydrophobic/hydrophillic) and thus (increase/decrease) an organic compound's water solubility.

All functional groups are hydrophillic and thus increase an organic compound's water solubility.