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42 Cards in this Set

  • Front
  • Back
What % of dry wt do living org have and which elem?
s
What d/ the current model of origins of life propose?
What were these organisms capable of?
s
Define polymerization?
How d/ most polymerization rxn occur by? Name this rxn?
s
What was a key development in origin of life?
s
What provides template for bilogical specificity?
s
Name two modern cells? define them?
s
Two unique charact of prok?
s
Name 3 domains?
s
Fnc of sexual reprod?What d/ increase of this lead to?
s
What does euk contain?
s
What d/ archae outwardly resemble? what in it closely resembles euk?
a
What is biological evol constrained by? It has a build in what?
a
What directs evol of species?
a
Define 1st law of thermo?Eqn?
a
What is enthapy? Symbol? Eqn?
a
2nd law states? what is converted here?
a
What determines sponteneity? Define exergonic and endergonic?
a
What is rate of rxn @ equil.?
a
What are examples of state fnc? What do they all depend on? How can they be measured? What c/b ignored?
aa
How d/ entropy of solute vary? What else varies? What d/ free energy change of chem rxn depend on?
a
Eqn of free E?
a
Eqn std free E? When is this eqn used when rxn is at what? Therefore what c/b calc from this?
a
What values c/v det from measurements of Keq @ 2 or more T? What varies with T? Eqn?
a
Define biochem std state? What activity is assigned to H2O and H+? Diff btw *G' and *G? What d/ activity equal?
a
What c/b change in an isolated system?
a
What is biochemistrty?
a
What elem are most abundant and what %?
a
Draw and ID fnc groups:
-aldehyde
-carbonyll
-carboxyllic A
-ester
-ether
-amide
-thiol
a
what d/ thermodynamics tell us? Define 1st, 2nd, and 3rd laws? Give eqn where necc
a
What is *G when *H and *S changes [Rewrite table].
a
What d/ equil constant show you? AT what [] will rxn proceed isomerization given @ e [P]/[R]=.00475=Keq?

-is rxn spont? if [DHAP]=R=2x10^-4 and [G3P]=P=3x10^-6?

-How do you solve for Keq given eqn?
-
a
How is *G determined? What doesnt *G tell you wrt rxn?
a
What kind of arrgmt d/ H2O have? Shape? Charge? polarity?
a
What kind of bond does water form?
a
List WA that are donors? List WB that are acceptors?
a
What does Hbond give water?Give example?How many Hbondsfor every molecule?
a
How many Hbonds d/ liq water form? whats liq mp?
a
Hbonds are one special type of what kind of interaxn?
a
What are cov. interaxns? Hbonds are special kind of what other interaxn?Strength?

What are van der waal forces? Name 2 dipoles and whats strength? What kind of contact d/ London disp. forces req?When do this play role?
a
Put bonds in order from least to most bond energies?
a
25. Online

-How d/ living sys restore itself to steady state?
a
-What d/ enzymne accelerate to reach what? How is this accomplished?
a